347973
氯代二硫代甲酸五氟苯基酯
96%
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关于此项目
线性分子式:
ClC(S)OC6F5
化学文摘社编号:
分子量:
262.58
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
96%
表单
liquid
折射率
n20/D 1.481 (lit.)
沸点
98-102 °C/50 mmHg (lit.)
密度
1.635 g/mL at 25 °C (lit.)
官能团
chloro
fluoro
SMILES字符串
Fc1c(F)c(F)c(OC(Cl)=S)c(F)c1F
InChI
1S/C7ClF5OS/c8-7(15)14-6-4(12)2(10)1(9)3(11)5(6)13
InChI key
DKFQHZNKNWNZCO-UHFFFAOYSA-N
应用
Pentafluorophenyl chlorothionoformate may be used:
- as derivatizing agent during radical-chain deoxygenations of primary alcohols
- as a reagent during the conversion of ribonucleoside to arabinonucleosides
- as reagent during the conversion of 6,8-diethyl-7-hydroxy-5-propyl-hexahydro-indolizin-3-one to O-6,8-diethyl-octahydro-3-oxo-5-propylindolizin-7-yl benzothioate
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
188.6 °F - closed cup
闪点(°C)
87 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
The invention of radical reactions. Part XXI. Simple methods for the radical deoxygenation of primary alcohols.
Barton DHR, et al.
Tetrahedron, 47(43), 8969-8994 (1991)
Wang et al.
Organic letters, 2(2), 227-230 (2000-05-18)
[structures: see text] A regio- and stereoselective glycosylation of ribose tetraester with persilylated alloxazine to give either beta-N1 or beta-N3 nucleosides is described. The N3 product is potentially of interest as a fluorescent nucleoside and is predicted to have the
Ramaiah Kumareswaran et al.
The Journal of organic chemistry, 69(26), 9151-9158 (2004-12-22)
Starting from succinamide and 1,2-heptadiene-4-ol, a racemic allene-aldehyde substrate, 20, suitable for R(3)SiSnR'(3)-mediated cyclization was synthesized in six steps and in 21% yield. Stereoselective cyclization (relative cis configuration at the new stereogenic centers of the homoallyl alcohol generated) proceeded smoothly
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