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347973

氯代二硫代甲酸五氟苯基酯

Name: 氯代二硫代甲酸五氟苯基酯
Brand: ALDRICH

96%

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关于此项目

线性分子式:

ClC(S)OC₆F₅

化学文摘社编号:

135192-53-9

分子量:

262.58

NACRES:

NA.22

PubChem Substance ID:

24861540

UNSPSC Code:

12352100

MDL number:

MFCD00075405

Assay:

96%

Form:

liquid

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属性

assay

96%

form

liquid

refractive index

n20/D 1.481 (lit.)

bp

98-102 °C/50 mmHg (lit.)

density

1.635 g/mL at 25 °C (lit.)

functional group

chloro, fluoro

SMILES string

Fc1c(F)c(F)c(OC(Cl)=S)c(F)c1F

InChI

1S/C7ClF5OS/c8-7(15)14-6-4(12)2(10)1(9)3(11)5(6)13

InChI key

DKFQHZNKNWNZCO-UHFFFAOYSA-N

说明

Application

Pentafluorophenyl chlorothionoformate may be used:

as derivatizing agent during radical-chain deoxygenations of primary alcohols
as a reagent during the conversion of ribonucleoside to arabinonucleosides
as reagent during the conversion of 6,8-diethyl-7-hydroxy-5-propyl-hexahydro-indolizin-3-one to O-6,8-diethyl-octahydro-3-oxo-5-propylindolizin-7-yl benzothioate

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405

Hazard Classifications

Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

188.6 °F - closed cup

flash_point_c

87 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tuning the acceptors in catalyzed cyclizations initiated by allenes. Silylstannylation/cyclization of allene-aldehydes for synthesis of polyalkylated indolizidines including 223A congeners.

Ramaiah Kumareswaran et al.

The Journal of organic chemistry, 69(26), 9151-9158 (2004-12-22)

Starting from succinamide and 1,2-heptadiene-4-ol, a racemic allene-aldehyde substrate, 20, suitable for R(3)SiSnR'(3)-mediated cyclization was synthesized in six steps and in 21% yield. Stereoselective cyclization (relative cis configuration at the new stereogenic centers of the homoallyl alcohol generated) proceeded smoothly

The invention of radical reactions. Part XXI. Simple methods for the radical deoxygenation of primary alcohols.

Barton DHR, et al.

Tetrahedron, 47(43), 8969-8994 (1991)

Regioselective synthesis of beta-N1- and beta-N3-alloxazine nucleosides

Wang et al.

Organic letters, 2(2), 227-230 (2000-05-18)

[structures: see text] A regio- and stereoselective glycosylation of ribose tetraester with persilylated alloxazine to give either beta-N1 or beta-N3 nucleosides is described. The N3 product is potentially of interest as a fluorescent nucleoside and is predicted to have the

全球贸易项目编号

货号	GTIN
347973-1G	04061837255076
347973-5G	04061837255083