349852
[3-(乙氧羰基)丙基]三苯基溴化膦
97%
别名:
NSC 269919
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关于此项目
线性分子式:
C2H5O2C(CH2)3P(C6H5)3Br
化学文摘社编号:
分子量:
457.34
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C24H26O2P.BrH/c1-2-26-24(25)19-12-20-27(21-13-6-3-7-14-21,22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h3-11,13-18H,2,12,19-20H2,1H3;1H/q+1;/p-1
SMILES string
[Br-].CCOC(=O)CCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI key
JPZMNVPVVYVXAD-UHFFFAOYSA-M
assay
97%
Quality Level
form
solid
reaction suitability
reaction type: C-C Bond Formation
mp
165-167 °C (lit.)
functional group
ester, phosphine
Application
Reactant for:
- Asymmetric synthesis of antihypercholesterolemic ezetimibe via Wittig reaction
- Wittig reactions
[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide can be used:
- As a reactant in the synthesis of spirocyclic GPR119 agonists.
- In the synthesis of cyclic acetal intermediate of azadirachtin, a terpenoid found in the neem tree Azadirachta indica.
- To prepare a catechin metabolite named 5-(3,4,5-trihydroxyphenyl)valeric acid.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Synthetic studies of azadirachtin. Synthesis of the cyclic acetal intermediate in the naturally occurring form
Nishikimi Y, et al.
The Journal of Organic Chemistry, 54(14), 3354-3359 (1989)
Design and synthesis of novel and potent GPR119 agonists with a spirocyclic structure
Harada K, et al.
Bioorganic & medicinal chemistry letters, 28(7), 1228-1233 (2018)
Inhibitory activity of catechin metabolites produced by intestinal microbiota on proliferation of HeLa cells
Hara-Terawaki A, et al.
Biological & Pharmaceutical Bulletin, 40(8), 1331-1335 (2017)
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