349852
[3-(乙氧羰基)丙基]三苯基溴化膦
97%
别名:
NSC 269919
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关于此项目
线性分子式:
C2H5O2C(CH2)3P(C6H5)3Br
化学文摘社编号:
分子量:
457.34
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
反应适用性
reaction type: C-C Bond Formation
mp
165-167 °C (lit.)
官能团
ester
phosphine
SMILES字符串
[Br-].CCOC(=O)CCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C24H26O2P.BrH/c1-2-26-24(25)19-12-20-27(21-13-6-3-7-14-21,22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h3-11,13-18H,2,12,19-20H2,1H3;1H/q+1;/p-1
InChI key
JPZMNVPVVYVXAD-UHFFFAOYSA-M
应用
Reactant for:
- Asymmetric synthesis of antihypercholesterolemic ezetimibe via Wittig reaction
- Wittig reactions
[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide can be used:
- As a reactant in the synthesis of spirocyclic GPR119 agonists.
- In the synthesis of cyclic acetal intermediate of azadirachtin, a terpenoid found in the neem tree Azadirachta indica.
- To prepare a catechin metabolite named 5-(3,4,5-trihydroxyphenyl)valeric acid.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Inhibitory activity of catechin metabolites produced by intestinal microbiota on proliferation of HeLa cells
Hara-Terawaki A, et al.
Biological & Pharmaceutical Bulletin, 40(8), 1331-1335 (2017)
Synthetic studies of azadirachtin. Synthesis of the cyclic acetal intermediate in the naturally occurring form
Nishikimi Y, et al.
The Journal of Organic Chemistry, 54(14), 3354-3359 (1989)
Design and synthesis of novel and potent GPR119 agonists with a spirocyclic structure
Harada K, et al.
Bioorganic & medicinal chemistry letters, 28(7), 1228-1233 (2018)
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