357340
铑
foil, thickness 0.025 mm, 99.9% trace metals basis
方案
99.9% trace metals basis
表单
foil
电阻率
4.33 μΩ-cm, 20°C
厚度
0.025 mm
沸点
3727 °C (lit.)
mp
1966 °C (lit.)
密度
12.41 g/cm3 (lit.)
SMILES字符串
[Rh]
InChI
1S/Rh
InChI key
MHOVAHRLVXNVSD-UHFFFAOYSA-N
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制备说明
190mg = 25×25mm
储存分类代码
11 - Combustible Solids
WGK
nwg
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Simon Duttwyler et al.
Science (New York, N.Y.), 339(6120), 678-682 (2013-02-09)
Piperidines are prevalent in natural products and pharmaceutical agents and are important synthetic targets for drug discovery and development. We report on a methodology that provides highly substituted piperidine derivatives with regiochemistry selectively tunable by varying the strength of acid
Stepan Chuprakov et al.
Journal of the American Chemical Society, 135(12), 4652-4655 (2013-03-13)
Readily available 1-mesyl-1,2,3-triazoles are efficiently converted into a variety of imidazolones and thiazoles by Rh(II)-catalyzed denitrogenative reactions with isocyanates and isothiocyanates, respectively. The proposed triazole-diazoimine equilibrium results in the formation of highly reactive azavinyl metal-carbenes, which react with heterocumulenes causing
Vutukuri Prakash Reddy et al.
Organic letters, 15(6), 1290-1293 (2013-02-28)
A straightforward and efficient method for the rhodium-catalyzed intermolecular oxidative cross-coupling of arenes and heteroarenes with thio- and selenophene derivatives (chalcogenophenes) via double C-H bond cleavage has been developed by using Cu(OAc)2/AgSbF6 as an oxidant. The reaction is applicable to
Rh/Pd catalysis with chiral and achiral ligands: domino synthesis of aza-dihydrodibenzoxepines.
Adam A Friedman et al.
Angewandte Chemie (International ed. in English), 52(37), 9755-9758 (2013-07-23)
Juliane Keilitz et al.
Organic letters, 15(5), 1148-1151 (2013-02-21)
A new enantioselective rhodium-catalyzed domino reaction is described that gives access to fused heterocycles by desymmetrization of alkyne-tethered cyclohexadienones. Two new C-C bonds and two stereocenters are formed in one step with good enantioselectivity. In contrast to prior reports, it
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