360996
1-三异丙基硅基-1-丙炔
98%
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线性分子式:
[(CH3)2CH]3SiC≡CCH3
化学文摘社编号:
分子量:
196.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
Form:
liquid
产品名称
1-三异丙基硅基-1-丙炔, 98%
InChI
1S/C12H24Si/c1-8-9-13(10(2)3,11(4)5)12(6)7/h10-12H,1-7H3
SMILES string
CC#C[Si](C(C)C)(C(C)C)C(C)C
InChI key
FDEZWWXTHRGNJD-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.4624 (lit.)
density
0.82 g/mL at 25 °C (lit.)
Application
1-(Triisopropylsilyl)-1-propyne may be used in the synthesis of 1,14-diaza[5]helicene. It may be used in the synthesis of 1- and 2-aza[6]helicene, via [2+2+2] cobalt catalyzed trimerization strategy.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Azahelicenes and other similar tri and tetracyclic helical molecules.
Dumitrascu F, et al.
ARKIVOC (Gainesville, FL, United States), 1, 1-32 (2010)
A straightforward route to helically chiral N-heteroaromatic compounds: practical synthesis of racemic 1,14-diaza[5]helicene and optically pure 1- and 2-aza[6]helicenes.
Jirí Mísek et al.
Angewandte Chemie (International ed. in English), 47(17), 3188-3191 (2008-03-14)
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