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Merck
CN

361011

Sigma-Aldrich

1H-1,2,3-三唑并[4,5-b]吡啶

98%

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关于此项目

经验公式(希尔记法):
C5H4N4
化学文摘社编号:
分子量:
120.11
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

98%

mp

208 °C (dec.) (lit.)

SMILES字符串

c1cnc2nn[nH]c2c1

InChI

1S/C5H4N4/c1-2-4-5(6-3-1)8-9-7-4/h1-3H,(H,6,7,8,9)

InChI key

VQNDBXJTIJKJPV-UHFFFAOYSA-N

一般描述

1H-1,2,3-Triazolo[4,5-b]pyridine belongs to the class of triazolopyridine. It reacts with europium under solvothermal conditions in pyridine to yield the homoleptic framework containing EuII centers that are icosahedrally coordinated by the 12 nitrogen atoms of six chelating ligands. The surface-enhanced Raman (SER) spectra of 1H-1,2,3-triazolo[4,5-b]pyridine adsorbed on silver hydrosols is studied in the region 3500-100cm-1.

应用

1H-1,2,3-Triazolo[4,5-b]pyridine (1,2,3-Triazolo(5,4-b)pyridine) may be used:
  • as starting reagent in the synthesis of 2,4,8,10-tetranitro-5H-pyrido[3″,2″:4′,5′] [1,2,3] triazolo [1′,2′:1,2] [1,2,3]- triazolo [5,4-b]-pyridin-6-ium inner salt
  • in the pesticide synthesis
  • as an entry to mesoionic heteropentalene derivatives

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The Chemistry of the [1, 2, 3] Triazolo [1, 5-a] pyridines: An Update.
Jones G and Abarca B.
Advances in Heterocyclic Chemistry, 100, 195-252 (2010)
(Infinity)3[Eu(Tzpy)2]: a homoleptic framework containing [Eu(II)N12] icosahedra.
Klaus Müller-Buschbaum et al.
Angewandte Chemie (International ed. in English), 46(23), 4385-4387 (2007-05-05)
Yifang Zhang et al.
Talanta, 219, 121356-121356 (2020-09-06)
Chemical derivatization of glycans is a common strategy to increase the analytical performance of MALDI-MS-based glycan profiling techniques. Hydrazide, one of the most popular tags, offers important advantages including allowing purification-free procedures. Several hydrazides have thus been used for glycomics
Helvetica Chimica Acta, 58, 1521-1521 (1975)
Surface-enhanced Raman spectroscopy of 1H-1, 2, 3-triazolo [4, 5-b] pyridine on silver sols.
Pergolese B and Bigotto A.
Journal of Raman Spectroscopy, 32(2), 109-114 (2001)

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