361755
(1,5-环辛二烯)二(三苯基膦)六氟磷酸铑二氯甲烷络合物(1:1)
别名:
NSC 179445
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关于此项目
经验公式（希尔记法）:
C45H44Cl2F6P3Rh
化学文摘社编号:
分子量:
965.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
InChI
1S/2C18H15P.C8H12.CH2Cl2.F6P.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;2-1-3;1-7(2,3,4,5)6;/h2*1-15H;1-2,7-8H,3-6H2;1H2;;/q;;;;-1;+1/b;;2-1-,8-7-;;;
SMILES string
[Rh+].ClCCl.F[P-](F)(F)(F)(F)F.[CH]1[CH]CC[CH][CH]CC1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
InChI key
FCVRPQBVWYQXFH-ISVFTUMHSA-N
reaction suitability
core: rhodium, reagent type: catalyst
mp
215 °C (lit.)
Application
Catalyst for:
- Polycyclotrimerization reactions
- Hydrosilylation and hydrogenation reactions
- Hydroformylation reactions
- Regioselective di- and trisilylation reactions
- Mannich and nitro-Mannich reactions
- Reductive alkylation reactions
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Chemistry Letters (Jpn), 881-881 (1988)
L Pauling
Proceedings of the National Academy of Sciences of the United States of America, 86(5), 1431-1433 (1989-03-01)
Consideration of the relation between bond length and bond number and the average atomic volume for different ways of packing atoms leads to the conclusion that the average ligancy of atoms in a metal should increase when a phase change
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