362174
(双环[2.2.1]庚-2,5-二烯)二氯钯(II)
98%
别名:
Dichloro (norbornadiene)palladium(II), NSC 176915, PdCl2(nbd)
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关于此项目
经验公式(希尔记法):
C7H8Cl2Pd
化学文摘社编号:
分子量:
269.46
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
方案
98%
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp
260 °C (dec.) (lit.)
SMILES字符串
Cl[Pd]Cl.[CH]1[CH]C2[CH][CH]C1C2
InChI
1S/C7H8.2ClH.Pd/c1-2-7-4-3-6(1)5-7;;;/h1-4,6-7H,5H2;2*1H;/q;;;+2/p-2
InChI key
BNCRZJHZZCMDNP-UHFFFAOYSA-L
应用
Catalyst for:
- Aerobic kinetic resolution of secondary alcohols
- Kinetic oxidative resolution of 1-phenyl ethanol
- Oxidative kinetic resolution-Claisen rearrangement sequence
- Aerobic oxidation of secondary alcohols
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
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