362220
2-叔丁基苯胺
98%
别名:
1-Amino-2-tert-butylbenzene, 2-(1,1-Dimethylethyl)aniline, 2-(1,1-Dimethylethyl)benzenamine, 2-tert-Butylphenylamine, o-tert-Butylaniline
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关于此项目
线性分子式:
(CH3)3CC6H4NH2
化学文摘社编号:
分子量:
149.23
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
228-634-5
MDL number:
产品名称
2-叔丁基苯胺, 98%
InChI key
AEIOZWYBDBVCGW-UHFFFAOYSA-N
InChI
1S/C10H15N/c1-10(2,3)8-6-4-5-7-9(8)11/h4-7H,11H2,1-3H3
SMILES string
CC(C)(C)c1ccccc1N
assay
98%
form
liquid
refractive index
n20/D 1.545 (lit.)
bp
123-124 °C/17 mmHg (lit.)
mp
−60 °C (lit.)
density
0.957 g/mL at 25 °C (lit.)
Quality Level
Application
2-tert-Butylaniline may be used in the preparation of 2,3-bis(2-tert-butylphenylimino)butane. It may be used in the preparation of two rotamers, anti- and syn-N,N′-bis-(2-tert-butylphenyl)naphthalene-1,4,5,8-tetracarboxylic diimides and their guest inclusion abilities were investigated.
General description
2-tert-Butylaniline is a sterically hindered aniline. 2-tert-Butylaniline participates in chemo- and regioselective copper-catalyzed cross-coupling reaction for the effective amination of 2-chlorobenzoic acids.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Difference in guest-inclusion abilities of anti-and syn-rotamers.
Kishikawa K, et al.
Journal of the Chemical Society. Perkin Transactions 1, 14, 2217-2221 (2000)
Xuefeng Mei et al.
The Journal of organic chemistry, 71(1), 142-149 (2006-01-04)
[reaction, structure: see text] A chemo- and regioselective copper-catalyzed cross-coupling reaction for effective amination of 2-chlorobenzoic acids with aniline derivatives has been developed. The method eliminates the need for acid protection and produces a wide range of N-aryl anthranilic acid
2, 3-Bis (2-tert-butylphenylimino) butane.
Ferreira LC, et al.
Acta Crystallographica Section E, Structure Reports Online, 62(10), o4282-o4284 (2006)
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