362433
N-甲氧基-N-甲羰基甲基膦酸二乙酯
96%
别名:
N-Methoxy-N-methyl-phosphonoacetamide diethyl ester, Diethyl N-methoxy-N-methylphosphonoacetamide
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关于此项目
线性分子式:
CH3ON(CH3)COCH2P(O)(OC2H5)2
化学文摘社编号:
分子量:
239.21
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1875865
Assay:
96%
Form:
liquid
InChI
1S/C8H18NO5P/c1-5-13-15(11,14-6-2)7-8(10)9(3)12-4/h5-7H2,1-4H3
SMILES string
CCOP(=O)(CC(=O)N(C)OC)OCC
InChI key
WYLRYBDGIILFIR-UHFFFAOYSA-N
assay
96%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
bp
90 °C/17 mmHg (lit.)
density
1.163 g/mL at 25 °C (lit.)
functional group
amine, phosphonate
Application
Wittig 羰基化试剂
Reactant for:
- Preparation of ring-expanded bryostatin analogs as antitumor agents
- Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization
- Rh2(II)-catalyzed nitro-group migration reactions
- Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions
- Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps
- Preparation of substituted furans via olefin cross-metathesis
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Aldrichimica Acta, 23, 43-43 (1990)
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