362719
二叔丁基膦
98%, liquid
别名:
HP ( t -Bu) 2, 双（ 叔 -丁基）膦
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关于此项目
线性分子式:
(CH3)3CPHC(CH3)3
化学文摘社编号:
分子量:
146.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
Beilstein/REAXYS Number:
1918492
产品名称
二叔丁基膦, 98%
InChI
1S/C8H19P/c1-7(2,3)9-8(4,5)6/h9H,1-6H3
SMILES string
CC(C)(C)PC(C)(C)C
InChI key
CRHWEIDCXNDTMO-UHFFFAOYSA-N
assay
98%
form
liquid
reaction suitability
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
density
0.79 g/mL at 25 °C (lit.)
functional group
phosphine
Application
二-叔丁基膦可用于多种配体的合成，如 Q-Phos 的 C-N、C-O 和 C-C 键的交叉偶联反应。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
No data available
flash_point_c
No data available
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Palladium-catalyzed ?-arylation of esters and amides under more neutral conditions.
Hama T, et al.
Journal of the American Chemical Society, 125(37), 11176-11177 (2003)
A novel functionalized P,C,P pincer ligand complex.
Grimm JC, et al.
Inorganic Chemistry Communications, 3(10), 511-514 (2000)
Catalytic C-S Cross-Coupling Reactions Employing Ni Complexes of Pyrrole-Based Pincer Ligands.
Venkanna GT, et al.
ACS Catalysis, 4(9), 2941-2950 (2014)
Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C? C, C? N, and C? O bond-forming cross-couplings.
Kataoka N, et al.
The Journal of Organic Chemistry, 67(16), 5553-5566 (2002)
Q-Phos.
William S
Aldrich Chemfiles, 7.10, 12-12 (2007)
相关内容
Phosphine Ligand Application Guide
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