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关于此项目
经验公式(希尔记法):
C4H5NOS2
化学文摘社编号:
分子量:
147.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1210145
Assay:
97%
Quality Segment
assay
97%
mp
92-94 °C (lit.)
solubility
methanol: soluble 25 mg/mL, clear, brownish-yellow to brown
functional group
thioether
SMILES string
CC1=CSC(=S)N1O
InChI
1S/C4H5NOS2/c1-3-2-8-4(7)5(3)6/h2,6H,1H3
InChI key
LOKDIDVKVVVVHK-UHFFFAOYSA-N
General description
3-Hydroxy-4-methyl-2(3H)-thiazolethione (HMTT) is a cyclic thiohydroxamic acid. It forms divalent complexes with the first-row d-block elements Co-Zn. Hydrated form of HMTT exhibits enhanced thermal stability and solubility compared with the anhydrous form. HMTT possess a chelating unit similar to pyrithione. Solid state chemistry of HMTT and its complexes with d-block elements has been reported.
Application
可用于 Barton 反应,通过对应酯的脱羧重排生成碳自由基。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
