363839
N-(叔丁氧基羰基)-对甲苯磺酰胺
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
CH3C6H4SO2NHCO2C(CH3)3
化学文摘社编号:
分子量:
271.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C12H17NO4S/c1-9-5-7-10(8-6-9)18(15,16)13-11(14)17-12(2,3)4/h5-8H,1-4H3,(H,13,14)
SMILES string
Cc1ccc(cc1)S(=O)(=O)NC(=O)OC(C)(C)C
InChI key
DUTLOVSBVBGNDM-UHFFFAOYSA-N
mp
121-123 °C (lit.)
solubility
chloroform: soluble 25 mg/mL, clear, colorless
functional group
amine
Quality Level
General description
在 Mitsunobu 条件下可直接与伯醇、仲醇和烯丙醇发生偶联反应生成各种磺酰基保护胺。
Application
N-(tert-Butoxycarbonyl)-p-toluenesulfonamide may be used in the preparation of enyne amide, precursor for Pauson-Khand reaction.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Tetrahedron Letters, 30, 5709-5709 (1989)
Toshio Honda et al.
The Journal of organic chemistry, 72(17), 6541-6547 (2007-07-31)
Diastereoselective formal synthesis of a monoterpene alkaloid, (-)-incarvilline, the key intermediate for the synthesis of (-)-incarvillateine, was achieved by using an intramolecular Pauson-Khand reaction of (S)-N-[(E)-2-butenyl]-N-(3-butynyl-2-methoxymethoxy)-p-toluenesulfonamide as a key step.
Use of the Mitsunobu reaction in the synthesis of orthogonally protected a, ?-diaminopropionic acids.
Kelleher F.
Tetrahedron Letters, 48(28), 4879-4882 (2007)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持