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Merck
CN

363901

2-氯-2-丙烯-1-醇

technical grade, 90%

别名:

2-氯丙烯醇

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关于此项目

线性分子式:
H2C=C(Cl)CH2OH
化学文摘社编号:
分子量:
92.52
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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产品名称

2-氯-2-丙烯-1-醇, technical grade, 90%

InChI

1S/C3H5ClO/c1-3(4)2-5/h5H,1-2H2

SMILES string

OCC(Cl)=C

InChI key

OSCXYTRISGREIM-UHFFFAOYSA-N

grade

technical grade

assay

90%

form

liquid

refractive index

n20/D 1.459 (lit.)

bp

133-134 °C (lit.)

density

1.162 g/mL at 25 °C (lit.)

functional group

chloro
hydroxyl

Quality Level

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Application

2-氯-2-丙烯-1-醇(2-氯丙烯醇)可以用作碳假单胞菌菌株生长的碳补充剂。 它可以用于制备2-(4-辛基苯基)-2-丙烯-1-醇。

General description

据报道,2-氯-2-丙烯-1-醇会在193 nm处发生光离解以生成CH2CCH2OH自由基中间体。 2-氯-2-丙烯-1-醇是在1,2,3-三氯丙烷的碱介导反应过程中形成的主要产物。 据报道,2-氯-2-丙烯-1-醇可与三氯化磷反应生成亚磷酸酯,而与氯化磷反应生成磷酸酯。

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

129.2 °F - closed cup

flash_point_c

54 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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分析证书(COA)

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Derivatives of phosphorus acids and 2-chloro-2-propen-1-ol.
Arbuzov BA, et al.
Russian Chemical Bulletin, 16(6), 1233-1238 (1967)
Arjun S Raman et al.
The Journal of chemical physics, 127(15), 154316-154316 (2007-10-24)
These velocity map imaging experiments characterize the photolytic generation of one of the two radical intermediates formed when OH reacts via an addition mechanism with allene. The CH2CCH2OH radical intermediate is generated photolytically from the photodissociation of 2-chloro-2-propen-1-ol at 193
J J van der Waarde et al.
Applied and environmental microbiology, 59(2), 528-535 (1993-02-01)
Three Pseudomonas strains capable of utilizing 2-chloroallylalcohol (2-chloropropenol) as the sole carbon source for growth were isolated from soil. The fastest growth was observed with strain JD2, with a generation time of 3.6 h. Degradation of 2-chloroallylalcohol was accompanied by
Kinetic studies of the homogeneous abiotic reactions of several chlorinated aliphatic compounds in aqueous solution.
Pagan M, et al.
Applied Geochemistry, 13(6), 779-785 (1998)
Ran Zhu et al.
Journal of medicinal chemistry, 50(25), 6428-6435 (2007-11-13)
Compound 1 (FTY720, Fingolimod) represents a new generation of immunosuppressant that modulates lymphocyte trafficking by interacting with the S1P(1) receptor. Compound 1 also provides a template molecule for studying the molecular biology of S1P receptors and related enzymes (kinases and

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