365157
1,1,3,3-四甲基-1,3-二苯基二硅胺烷
96%
别名:
1,3-联苯基四甲基二硅氮烷, DPTMDS
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关于此项目
线性分子式:
[C6H5Si(CH3)2]2NH
化学文摘社编号:
分子量:
285.53
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
222-372-5
Beilstein/REAXYS Number:
2738118
MDL number:
产品名称
1,1,3,3-四甲基-1,3-二苯基二硅胺烷, 96%
InChI key
HIMXYMYMHUAZLW-UHFFFAOYSA-N
InChI
1S/C16H23NSi2/c1-18(2,15-11-7-5-8-12-15)17-19(3,4)16-13-9-6-10-14-16/h5-14,17H,1-4H3
SMILES string
C[Si](C)(N[Si](C)(C)c1ccccc1)c2ccccc2
assay
96%
form
liquid
refractive index
n20/D 1.538 (lit.)
bp
96-100 °C/0.1 mmHg (lit.)
density
0.985 g/mL at 25 °C (lit.)
Quality Level
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Application
1,1,3,3-Tetramethyl-1,3-diphenyldisilazane can be used:
- As a starting material for the synthesis of its substitution products with the tetrachlorides of silicon and tin.
- To prepare Cu-, Zn- and H2-phthalocyanines using phthalimide.
- As a pre-column deactivation agent prior to the determination of the fatty acids by GC-MS.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Silazanes plus MCl4-substitution vs. rearrangement reactions
Lehnert C, et al.
Chemistry of Heterocyclic Compounds, 42(12), 1574-1584 (2006)
Convenient synthesis of phthalocyanines with disilazanes under mild conditions.
Uchida H, et al.
ARKIVOC (Gainesville, FL, United States), 11, 17-23 (2005)
Dorothee Eibler et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1046, 138-146 (2017-02-10)
Between 2008 and 2011, four polar bears (Ursus maritimus) from the Greenland population swam and/or drifted on ice to Iceland where they arrived in very poor body condition. Body fat resources in these animals were only between 0% and 10%
Simon Hammann et al.
Analytical and bioanalytical chemistry, 407(30), 9019-9028 (2015-10-07)
Triacylglycerols represent the major part (>90%) in most plant oils and have to be eliminated, when the minor compounds such as phytosterols or tocopherols should be analyzed. Here, we used an all liquid-liquid chromatographic technique, countercurrent chromatography (CCC), to fractionate
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