368539
甲硫甲基苯基砜
99%
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关于此项目
线性分子式:
C6H5SO2CH2SCH3
化学文摘社编号:
分子量:
202.29
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
InChI
1S/C8H10O2S2/c1-11-7-12(9,10)8-5-3-2-4-6-8/h2-6H,7H2,1H3
SMILES string
CSCS(=O)(=O)c1ccccc1
InChI key
XBGGZYQBIQAYII-UHFFFAOYSA-N
assay
99%
mp
85-87 °C (lit.)
General description
Methylthiomethyl phenyl sulfone is a sulfone derivative.
Application
Methylthiomethyl phenyl sulfone may be employed:
- as nucleophilic and electrophilic building block, in the asymmetric synthesis of 6-N-benzoyl-5′-O-benzyl-2′-deoxyadenosine and its anomer
- in the synthesis of various multidentate methylthio arylethynes (MTA) derivatives
- as starting reagent in the preparation of methylthio arylbutadiynes (Ar-C=C-C=C-SCH3)
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Rigid, conjugated and shaped arylethynes as mediators for the assembly of gold nanoparticles.
Yan H, et al.
Journal of Materials Chemistry, 21(6), 1890-1901 (2011)
B M Trost et al.
Carbohydrate research, 202, 1-12 (1990-07-15)
An asymmetric synthesis of 6-N-benzoyl-5'-O-benzyl-2'-deoxyadenosine and its a anomer from non-carbohydrate building blocks is achieved in 7 steps. The sequence builds the basic structures using bis(methylthio)methane and methylthiomethyl phenyl sulfone as both nucleophilic and electrophilic building blocks, a feature that
Efficient One-Pot Preparation of Methylthio Arylbutadiynes by Double Elimination Protocol.
Su Q, et al.
Synthetic Communications, 43(19), 2648-2655 (2019)
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