37275
(+)-二氢香芹酮
mixture of isomers
别名:
(2R,5R)-5-异丙烯基-2-甲基环己酮
表单
liquid
旋光性
[α]20/D +20±2°, neat
组成
n-(+)-dihydrocarvone, ~77%
iso-(+)-dihydrocarvone, ~20%
折射率
n20/D 1.471
密度
0.928 g/mL at 20 °C (lit.)
官能团
ketone
SMILES字符串
CC1CCC(CC1=O)C(C)=C
InChI
1S/C10H16O/c1-7(2)9-5-4-8(3)10(11)6-9/h8-9H,1,4-6H2,2-3H3
InChI key
AZOCECCLWFDTAP-UHFFFAOYSA-N
一般描述
(+)-二氢香豆素，一种在香芹籽油中发现的单萜化合物，是合成倍半萜烯的关键结构单元。 它通常通过香芹酮的氢化反应或柠檬烯的氧化反应进行生产。
应用
(+)-二氢香豆素可用于以下过程：
- 合成1,2,4,5-四恶烷，其表现出强效抗疟疾活性。
- 通过氧化反应合成环氧内酯，其可与ε-己内酯发生共聚反应，形成具有形状记忆性能的交联共聚物。
- 合成α-香附酮，一种具有强效杀虫活性的桉叶烷型倍半萜类化合物。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
215.6 °F - closed cup
闪点(°C)
102 °C - closed cup
个人防护装备
Eyeshields, Gloves
The structure and antimalarial activity of dispiro-1, 2, 4, 5-tetraoxanes derived from (+)-dihydrocarvone.
Dong Y, et al.
Bioorganic & Medicinal Chemistry Letters, 20(22), 6359-6361 (2010)
Oxidized dihydrocarvone as a renewable multifunctional monomer for the synthesis of shape memory polyesters.
Lowe JR, et al.
Biomacromolecules, 10(7), 2003-2008 (2009)
Dan Jin et al.
Scientific reports, 10(1), 3309-3309 (2020-02-26)
Cannabis research has historically focused on the most prevalent cannabinoids. However, extracts with a broad spectrum of secondary metabolites may have increased efficacy and decreased adverse effects compared to cannabinoids in isolation. Cannabis's complexity contributes to the length and breadth
Insecticidal activity of sesquiterpenes skeleton synthesized by the conventional Robinson annulations reaction on Drosophila melanogaster.
Alarcon J, et al.
Industrial Crops and Products, 42, 268-272 (2013)
N-functionalization of dihydrocarvone: Obtaining aminocyclohexane derivatives and their spectrometric study.
Kouznetsov VV and Stashenko EE.
Journal of the Chilean Chemical Society, 50(3), 559-563 (2005)
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