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374288

4-氯苯甲酰氯

95%

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关于此项目

线性分子式:
ClC6H4COCl
化学文摘社编号:
122-01-0
分子量:
175.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24863295
EC Number:
204-515-3
Beilstein/REAXYS Number:
471606
MDL number:
MFCD00000686
Assay:
95%
Form:
liquid
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assay

95%

form

liquid

refractive index

n20/D 1.578 (lit.)

bp

102-104 °C/11 mmHg (lit.)

mp

11-14 °C (lit.)

density

1.365 g/mL at 20 °C (lit.)

functional group

acyl chloride, chloro

SMILES string

ClC(=O)c1ccc(Cl)cc1

InChI

1S/C7H4Cl2O/c8-6-3-1-5(2-4-6)7(9)10/h1-4H

InChI key

RKIDDEGICSMIJA-UHFFFAOYSA-N

General description

4-Chlorobenzoyl chloride is an acyl chloride. It reacts with 2-amino-2-seleno-5,5-dimethyl-1,3,2-dioxaphosphorinane to yield the respective N-acyl selenophosphoramides.

Application

4-Chlorobenzoyl chloride may be used in the following studies:
  • Acylation of benzene using different solid acid catalysts such as dodecatungstophosphoric acid (DTPA), DTPA/K-10 clay, K-10, Amberlite, Amberlyst-15, Indion-130, Filtrol-24 clay and sulfated zirconia.
  • Preparation of 1-(4-chlorobenzoyl)-2, 7-dimethoxynaphthalene.
  • Preparation of 4-chlorobenzoyl CoA, via reaction with CoA in KHCO3 buffer.
  • Preparation of 1-aryloxyacetyl-4-(4-chlorobenzoyl)-semicarbazides.

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pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314,H412

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

221.0 °F - closed cup

flash_point_c

105 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number
STBG8248
BCBN4644V
BCBJ1251V
1449288
1449287

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A Facile Method to 1, 4-Diacyl Semicarbazides: Syntheses of 1-Aryloxyacetyl-4-(4-Chlorobenzoyl)-Thiosemicarbazides and Semicarbazides.
Wang X, et al.
Synthetic Communications, 30(18), 3405-3411 (2000)
Friedel-Crafts acylation using sulfated zirconia catalyst.
Yadav GD and Pujari AA.
Green Chemistry, 1(2), 69-74 (1999)
Ryosuke Mitsui et al.
Acta crystallographica. Section E, Structure reports online, 64(Pt 7), o1278-o1278 (2008-01-01)
In the title compound, C(19)H(15)ClO(3), the dihedral angle between the naphthalene ring system and the benzene ring is 72.06 (7)°. The 4-chloro-phenyl group and the carbonyl group are almost coplanar. An inter-molecular C-H⋯O hydrogen bond is formed between an H atom
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全球贸易项目编号

货号GTIN
374288-25ML04061831834703
374288-2L04061836692117