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线性分子式:
CH3O2CCH2CH(OH)CO2CH3
化学文摘社编号:
分子量:
162.14
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
432-310-0
Beilstein/REAXYS Number:
1724363
MDL number:
Assay:
98%
产品名称
(S)-(-)-苹果酸二甲酯, 98%
InChI key
YSEKNCXYRGKTBJ-BYPYZUCNSA-N
InChI
1S/C6H10O5/c1-10-5(8)3-4(7)6(9)11-2/h4,7H,3H2,1-2H3/t4-/m0/s1
SMILES string
COC(=O)C[C@H](O)C(=O)OC
assay
98%
optical activity
[α]20/D −6.5°, neat
refractive index
n20/D 1.435 (lit.)
density
1.223 g/mL at 25 °C (lit.)
functional group
ester
hydroxyl
storage temp.
2-8°C
Quality Level
Application
(S)-(-)-苹果酸二甲酯可作为起始试剂用于合成 (-)-郁金香内酯B。其酯基向醇的选择性还原可通过在四氢硼酸钠的存在下使用硼烷二甲基硫醚络合物(BMS)完成。
该手性合成子已被用于制备花生四烯酸的细胞色素P450代谢产物,以及具有HIV-1蛋白酶抑制潜能的环状的环丁砜。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
131.0 °F
flash_point_c
55 °C
ppe
Eyeshields, Gloves
法规信息
危险化学品
此项目有
Falck, J.R. et al.
Tetrahedron Letters, 33, 4893-4893 (1992)
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