374342
N,N′,N′′-三(对甲苯磺酰)二乙撑三胺 二钠盐
97%
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线性分子式:
[CH3C6H4SO2N(Na)CH2CH2]2NSO2C6H4CH3
化学文摘社编号:
分子量:
609.69
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3585044
Assay:
97%
assay
97%
mp
275 °C (dec.) (lit.)
solubility
95% ethanol: soluble 25 mg/mL, clear, colorless to yellow
functional group
amine, sulfonamide
SMILES string
Cc1ccc(cc1)S(=O)(=O)N([Na])CCN(CCN([Na])S(=O)(=O)c2ccc(C)cc2)S(=O)(=O)c3ccc(C)cc3
InChI
1S/C25H29N3O6S3.2Na/c1-20-4-10-23(11-5-20)35(29,30)26-16-18-28(37(33,34)25-14-8-22(3)9-15-25)19-17-27-36(31,32)24-12-6-21(2)7-13-24;;/h4-15H,16-19H2,1-3H3;;/q-2;2*+1
InChI key
HWXFIPYUNYRUJA-UHFFFAOYSA-N
General description
N,N′,N′′-Tritosyldiethylenetriamine is a tosyl derivative and its complexation with Ag(I) and Cu(II) is reported.
Application
N,N′,N′′-Tritosyldiethylenetriamine disodium salt may be used in the preparation of tritosylate of 1,4,7-triazacyclononane, via reaction with 1,2-dibromoethane in DMF. It may be used in the preparation of 1,4,7-triazacyclononane, via reaction with ditosyl derivative of 1,2-ethanediol.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Stability constants of some macrocyclic complexes of Ag (I) and Cu (II) in mixed solvents by potentiometry.
Sil A, et al.
Supramolecular Chemistry, 15(6), 451-457 (2003)
Acid dissociation kinetics of copper (II) complexes of 1, 4, 7-triazacyclononane ([9] aneN3).
Hay RW and Pujari MP.
Transition Met. Chem. (London), 17(2), 81-83 (1992)
Thorsten Allscher et al.
Acta crystallographica. Section E, Structure reports online, 65(Pt 8), o1734-o1734 (2009-01-01)
The title compound, C(6)H(16)N(3) (+)·Br(-), is the bromide of the monoprotonated aza-macrocyclic triamine 1,4,7-triaza-cyclo-nonane (tacn). The threefold axis of the triamine is broken by the protonation of one of the three amine functions. The ammonium proton is bonded in an
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| 货号 | GTIN |
|---|---|
| 374342-25G | 04061832853512 |