374377
2-(三苯基正膦基)丙醛
98%
别名:
1-Formylethylidenetriphenylphosphorane
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关于此项目
线性分子式:
(C6H5)3P=C(CH3)CHO
化学文摘社编号:
分子量:
318.35
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352114
MDL number:
Assay:
98%
Form:
powder
Quality Segment
assay
98%
form
powder
reaction suitability
reaction type: C-C Bond Formation
mp
219-221 °C (lit.)
functional group
aldehyde, phosphine
SMILES string
CC(C=O)=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C21H19OP/c1-18(17-22)23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3
InChI key
VHUQEFAWBCDBSC-UHFFFAOYSA-N
Application
Reactant for:
- Preparation of acitretin analogs with antitumor activity
- Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
- Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
- Wittig reactions
- Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
- Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH
存储类别
11 - Combustible Solids
怎么回事？
WGK 3
闪点 (F)
Not applicable
闪点 (°C)
Not applicable
PPE（个人防护设备）
Eyeshields, Gloves, type N95 (US)