方案
97%
表单
liquid
折射率
n20/D 1.463 (lit.)
沸点
130-131 °C/14 mmHg (lit.)
密度
1.362 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CCOP(=O)(OCC)C(Cl)(Cl)Cl
InChI
1S/C5H10Cl3O3P/c1-3-10-12(9,11-4-2)5(6,7)8/h3-4H2,1-2H3
InChI key
RVAQSYWDOSHWGP-UHFFFAOYSA-N
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一般描述
Addition reaction of diethyl (trichloromethyl)phosphonate to olefins by non-chain catalytic reactions catalyzed by copper amine complexes has been reported. Irradiation of diethyl (trichloromethyl)phosphonate in MeCN is reported to afford corresponding monoesters and olefins, via photochemical type II elimination reaction.
应用
Diethyl (trichloromethyl)phosphonate may be used in the synthesis of chlorovinyl phosphonates via reaction with aldehydes and ketones.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Addition of diethyl trichloromethylphosphonate to olefins catalysed by copper complexes.
Villemin D, et al.
Tetrahedron Letters, 35(21), 3537-3538 (1994)
A novel synthesis of phosphonates from diethyl (trichloromethyl) phosphonate.
Lowen GT and Almond MR.
The Journal of Organic Chemistry, 59(!6), 4548-4550 (1994)
Photochemical type I and II elimination reactions of dialkyl (trichloromethyl) phosphonates.
Suzuki N, et al.
Bulletin of the Chemical Society of Japan, 53(5), 1421-1424 (1980)
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