374733
2,6-二异丙基苯胺
97%
别名:
2,6-Bis(1-methylethyl)benzenamine, 2,6-Bis(propan-2-yl)aniline, 2,6-Diisopropylphenylamine
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关于此项目
线性分子式:
[(CH3)2CH]2C6H3NH2
化学文摘社编号:
分子量:
177.29
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
246-305-4
Beilstein/REAXYS Number:
2208763
MDL number:
产品名称
2,6-二异丙基苯胺, 97%
InChI key
WKBALTUBRZPIPZ-UHFFFAOYSA-N
InChI
1S/C12H19N/c1-8(2)10-6-5-7-11(9(3)4)12(10)13/h5-9H,13H2,1-4H3
SMILES string
CC(C)c1cccc(C(C)C)c1N
vapor pressure
<0.01 mmHg ( 20 °C)
assay
97%
form
liquid
refractive index
n20/D 1.532 (lit.)
bp
257 °C (lit.)
mp
−45 °C (lit.)
density
0.94 g/mL at 25 °C (lit.)
Quality Level
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Application
2,6-二异丙基苯胺可用于制备基于萘二酰亚胺（NDI）的有机催化剂。
2,6-二异丙基苯胺可用于制备多配位希夫碱配体前体。它可用于制备NSN-供体前配体4,5-双(2,6-二异丙基苯胺基)-2,7-二叔丁基-9,9-二甲基硫杂蒽。它可用于制备N-杂环碳烯配合物，以用于无环酮的α-芳基化、卤代芳烃的胺化和水性Suzuki偶联反应。
General description
2,6-二异丙基苯胺是一种胺。它在对甲苯磺酸存在的情况下与三乙酰甲烷在甲苯中发生缩合，生成3-[1-(2,6-二异丙基苯基氨基)亚乙基]戊烷-2,4-二酮。
2,6-二异丙基苯胺是一种重要的有机中间体，广泛应用于塑料和染料的合成。
2,6-二异丙基苯胺是一种重要的有机中间体，广泛应用于塑料和染料的合成。
2,6-二异丙基苯胺是一种芳香胺。它与大体积的酰氨基吡啶基（Ap）和脒基（Amd）配体负载的双(三甲基甲硅烷基甲基)钇络配合物反应，生成烷基苯胺基钇。该反应涉及TMS (三甲基硅烷)的消除。
2,6-二异丙基苯胺是一种重要的有机中间体，广泛应用于塑料和染料的合成。 .
2,6-二异丙基苯胺是一种重要的有机中间体，广泛应用于塑料和染料的合成。 .
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 2
ppe
Eyeshields, Gloves
Characterization and performance of Pd-La/spinel catalyst for preparation of 2, 6-diisopropylaniline
Ruixia J, et al.
Applied Catalysis A: General, 250(2), 209-220 (2003)
Electron-deficient naphthalene diimides as efficient planar Π-acid organocatalysts for selective oxidative C-C coupling of 2, 6-di-tert-butylphenol: A temperature effect.
Ke H, et al.
J. Mol. Catal. A: Chem., 385, 26-30 (2014)
Christoph Fleckenstein et al.
Chemical communications (Cambridge, England), (27), 2870-2872 (2007-07-05)
Sulfonated, water-soluble imidazolium and imidazolinium salts were synthesized and the respective Pd-complexes with N,N'-bis(2,6-dialkyl-4-SO(3)(-)-phenyl)imidazol-2-ylidene and N,N'-bis(2,6-dialkyl-4-SO(3)(-)-phenyl)-4,5-dihydroimidazol-2-ylidene ligands were applied in aqueous Suzuki coupling reactions of aryl chlorides.
Kouki Matsubara et al.
The Journal of organic chemistry, 72(14), 5069-5076 (2007-06-15)
Arylation of both acyclic ketones and primary and secondary amines was achieved using a new, simple, stable, and easy-to-access nickel(II)-halide complex bearing mixed PPh3/N-heterocyclic carbene ligands as a catalyst precursor. Acyclic ketones were first arylated at the alpha-position with the
Reactions of Bis (alkyl) yttrium Complexes Supported by Bulky N, N Ligands with 2, 6-Diisopropylaniline and Phenylacetylene.
Karpov AV, et al.
Organometallics, 31(15), 5349-5357 (2012)
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