376388
(R)-(+)-胡薄荷酮
≥90%
别名:
(+)-蒲勒酮, (R)-(+)-长叶薄荷酮, (R)-2-异亚丙基-5-甲基环己酮, 长叶薄荷酮
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关于此项目
经验公式（希尔记法）:
C10H16O
化学文摘社编号:
分子量:
152.23
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-943-2
Beilstein/REAXYS Number:
2040703
MDL number:
Assay:
≥90%
Form:
liquid
vapor pressure
138 mmHg ( 25 °C)
assay
≥90%
form
liquid
optical activity
[α]20/D +23.5°, neat
refractive index
n20/D 1.486 (lit.)
bp
224 °C (lit.)
density
0.937 g/mL at 25 °C (lit.)
functional group
ketone
SMILES string
C[C@@H]1CC\C(=C(\C)C)C(=O)C1
InChI
1S/C10H16O/c1-7(2)9-5-4-8(3)6-10(9)11/h8H,4-6H2,1-3H3/t8-/m1/s1
InChI key
NZGWDASTMWDZIW-MRVPVSSYSA-N
General description
( R )-(+)-长叶薄荷酮，在薄荷油的精油中发现的一种单萜酮， 可诱发流产。
Application
( R )-(+)-长叶薄荷酮可作为起始原料合成：
- (2S,4R,6R,8S)-2,4,8-三甲基-1,7-二氧杂环己酮 [5.5] 十一烷，螺缩酮
- ( R )-(+)-香茅酸，制备亮氨酸-d 的中间体 3
- (+)-法西亭碱，石松生物碱
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
179.6 °F - closed cup
flash_point_c
82 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of (2S, 4S)-and (2S, 4R)-[5,5,5-2H3] leucine from (R)-pulegone.
Hill RK, et al.
Canadian Journal of Chemistry, 72(1), 110-113 (1994)
Total Synthesis of (+)-Fawcettidine.
Kozak JA and Dake GR.
Angewandte Chemie (International Edition in English), 47(22), 4221-4223 (2008)
Metabolism of (R)-(+)-pulegone in F344 rats.
Chen LJ, et al.
Drug Metabolism and Disposition, 29(12), 1567-1577 (2001)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 376388-5G | 04061831835175 |
| 376388-100G | 04061837385001 |