方案
≥99%
表单
powder
自燃温度
1198 °F
反应适用性
reagent type: Lewis acid
core: beryllium
reagent type: catalyst
电阻率
4.46 μΩ-cm, 20°C
粒径
−325 mesh
沸点
2970 °C (lit.)
mp
1278 °C (lit.)
密度
1.85 g/mL at 25 °C (lit.)
SMILES字符串
[Be]
InChI
1S/Be
InChI key
ATBAMAFKBVZNFJ-UHFFFAOYSA-N
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应用
Starting material for novel sterically encumbered arylberyllium compounds.
Reagent for synthesis of:
Reagent for:
Reagent for synthesis of:
- Beryllium phthalocyanine and its derivatives
- Catalyst with cerium oxide for oxidative coupling of methane
- Organoberyllium compounds
Reagent for:
- Metal mediated dechlorination
- Stereoselective Horner-Wadsworth-Emmons reactions
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 1B Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
4.1B - Flammable solid hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
新产品
此项目有
K. Otsuka, et al.,
Chemistry Letters (Jpn), 9, 1835-1838 (1987)
David D Díaz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(9), 2593-2606 (2006-01-10)
A highly regio- and stereoselective intramolecular [1,5]-hydrogen-transfer process is described. Treatment of gamma-benzyl-protected Co2(CO)6-alpha,gamma-acetylenic diols with BF3 x OEt2 provides bis-homopropargylic alcohols. The reaction occurs within seconds, tolerates a wide range of functionalities, and provides good yields. When the ether
I. I. Lapkin and S. V. Sinani,
Zh. Obshch. Khim., 57, 372-375 (1987)
Excitation functions for 7Be, 22,24Na production in Mg and Al by deuteron irradiations up to 50 MeV.
A Hermanne et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 70(12), 2763-2772 (2012-10-10)
New experimental data for production of (7)Be and (22,24)Na in deuteron irradiation of (nat)Mg and Al up to 50 MeV are presented. The induced activity, measured with HPGe spectroscopy, allows us to determine excitation functions of (nat)Mg(d,x) and (27)Al(d,x) reactions
Mark Niemeyer et al.
Inorganic chemistry, 36(21), 4688-4696 (2001-10-24)
The use of the terphenyl substituent -C(6)H(3)-2,6-Mes(2) (abbreviated Ar) has permitted the synthesis of several new low-coordinate beryllium compounds. Reaction of 1 equiv of LiAr with BeCl(2)(OEt(2))(2) or BeBr(2)(OEt(2))(2) (1) gives the monomeric complexes ArBeX(OEt(2)) (X = Cl (2); Br
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