InChI key
ATBAMAFKBVZNFJ-UHFFFAOYSA-N
InChI
1S/Be
SMILES string
[Be]
assay
≥99%
form
powder
autoignition temp.
1198 °F
reaction suitability
reagent type: Lewis acid
core: beryllium, reagent type: catalyst
resistivity
4.46 μΩ-cm, 20°C
particle size
−325 mesh
bp
2970 °C (lit.)
mp
1278 °C (lit.)
density
1.85 g/mL at 25 °C (lit.)
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Application
Starting material for novel sterically encumbered arylberyllium compounds.
Reagent for synthesis of:
Reagent for:
Reagent for synthesis of:
- Beryllium phthalocyanine and its derivatives
- Catalyst with cerium oxide for oxidative coupling of methane
- Organoberyllium compounds
Reagent for:
- Metal mediated dechlorination
- Stereoselective Horner-Wadsworth-Emmons reactions
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 1B Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 - STOT SE 3
target_organs
Respiratory system
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
新产品
此项目有
K. Otsuka, et al.,
Chemistry Letters (Jpn), 9, 1835-1838 (1987)
David D Díaz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(9), 2593-2606 (2006-01-10)
A highly regio- and stereoselective intramolecular [1,5]-hydrogen-transfer process is described. Treatment of gamma-benzyl-protected Co2(CO)6-alpha,gamma-acetylenic diols with BF3 x OEt2 provides bis-homopropargylic alcohols. The reaction occurs within seconds, tolerates a wide range of functionalities, and provides good yields. When the ether
I. I. Lapkin and S. V. Sinani,
Zh. Obshch. Khim., 57, 372-375 (1987)
Mark Niemeyer et al.
Inorganic chemistry, 36(21), 4688-4696 (2001-10-24)
The use of the terphenyl substituent -C(6)H(3)-2,6-Mes(2) (abbreviated Ar) has permitted the synthesis of several new low-coordinate beryllium compounds. Reaction of 1 equiv of LiAr with BeCl(2)(OEt(2))(2) or BeBr(2)(OEt(2))(2) (1) gives the monomeric complexes ArBeX(OEt(2)) (X = Cl (2); Br
V. K. Tandon and R. B. Chhor,
Letters in Organic Chemistry, 1, 40-42 (2004)
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