379107
3-(二甲氨基)-5,5-二甲基-2-环己烯-1-酮
99%
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关于此项目
经验公式（希尔记法）:
C10H17NO
化学文摘社编号:
分子量:
167.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
Form:
solid
InChI
1S/C10H17NO/c1-10(2)6-8(11(3)4)5-9(12)7-10/h5H,6-7H2,1-4H3
SMILES string
CN(C)C1=CC(=O)CC(C)(C)C1
InChI key
XHNTVKASLQLNFM-UHFFFAOYSA-N
assay
99%
form
solid
mp
95-96 °C (lit.)
Application
3-(Dimethylamino)-5,5-dimethyl-2-cyclohexen-1-one may be used for trapping the o-quinone methide intermediate, formed during the photolysis of the quinones.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Yugang Chen et al.
The Journal of organic chemistry, 71(16), 6053-6060 (2006-07-29)
Upon exposure to visible light, 2-pyrrolidino-substituted 3,6-dimethyl-1,4-benzoquinones photocyclize to give benzoxazolines with quantum yields of 0.07-0.10 in CH2Cl2, 0.02-0.04 in CH3CN, and <0.01 in 30% aq CH3CN. With carboxylate or phenolate leaving groups incorporated via coupling to a 5-hydroxymethyl group
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