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Merck
CN

379123

4,5-二溴-2,7-二-叔丁基-9,9-二甲基氧杂蒽

97%

别名:

4,5-二溴-2,7-二叔丁基-9,9-二甲基-9H-氧杂蒽, 4,5-二溴-2,7-双(1,1-二甲基乙基)-9,9-二甲基-9H-氧杂蒽

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关于此项目

经验公式(希尔记法):
C23H28Br2O
化学文摘社编号:
分子量:
480.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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产品名称

4,5-二溴-2,7-二-叔丁基-9,9-二甲基氧杂蒽, 97%

InChI

1S/C23H28Br2O/c1-21(2,3)13-9-15-19(17(24)11-13)26-20-16(23(15,7)8)10-14(12-18(20)25)22(4,5)6/h9-12H,1-8H3

SMILES string

CC(C)(C)c1cc(Br)c2Oc3c(Br)cc(cc3C(C)(C)c2c1)C(C)(C)C

InChI key

OJJSJAIHWCFVBK-UHFFFAOYSA-N

assay

97%

form

solid

mp

260-262 °C (lit.)

functional group

bromo

Quality Level

Application

4,5-二溴-2,7-二丁基-9,9-二甲基呫吨可用于合成:
  • 2,6-二丁基-4,5-二碘-9,9-二甲基呫吨
  • 新的非供体配体,4,5-双(2,6-二异丙基苯胺基)-2,7-二丁基-9,9-二甲基呫吨
  • 双(二乙氨基)xantphos,通过一锅金属化反应并用双(二乙氨基)氯膦淬灭
4,5-二溴-2,7-二丁基-9,9-二甲基呫吨可用作合成4,5-(N,N′-双环己基氨基)-2,7-二丁基-9,9-二甲基呫吨和带有两个四噻吩部分的寡噻吩镊子分子的起始试剂。

General description

4,5-二溴-2,7-二丁基-9,9-二甲基呫吨是杂环结构单元。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

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Lisa D Julian et al.
Journal of the American Chemical Society, 132(39), 13813-13822 (2010-09-16)
We report a rhodium catalyst that exhibits high reactivity for the hydroamination of primary aminoalkenes that are unbiased toward cyclization and that possess functional groups incompatible with more electrophilic hydroamination catalysts. The rhodium catalyst contains an unusual diaminophosphine ligand (L1)
Synthesis, structure, and properties of aromatic ring-layered polymers containing ferrocene as a terminal unit.
Morisaki Y, et al.
Journal of Inorganic and Organometallic Polymers and Materials, 19(1), 104-112 (2009)
Dimethylxanthene-and dibenzofuran-diamido complexes of titanium.
Porter RM and Danopoulos AA.
Polyhedron, 25(4), 859-863 (2006)
Ryo Takita et al.
Organic letters, 10(21), 5003-5005 (2008-10-09)
An oligothiophene tweezer molecule, which has two quaterthiophene moieties connected to create an electrochemically activated hinge, has been synthesized. Two-electron oxidation of the tweezer molecule produces an intramolecular pi-dimer between the two oligothiophene moieties at room temperature as confirmed by
Extremely Stable Thorium (IV) Dialkyl Complexes Supported by Rigid Tridentate 4, 5-Bis (anilido) xanthene and 2, 6-Bis (anilidomethyl) pyridine Ligands.
Cruz CA, et al.
Organometallics, 26(3), 692-701 (2007)

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