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Merck
CN

38221

二异辛基二硫代次膦酸

technical, ~85% (T)

别名:

双(2,4,4-三甲基戊基)二硫代次膦酸

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关于此项目

经验公式(希尔记法):
C16H35PS2
化学文摘社编号:
分子量:
322.55
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
Assay:
~85% (T)
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grade

technical

assay

~85% (T)

refractive index

n20/D 1.507

density

0.95 g/mL at 20 °C (lit.)

SMILES string

CC(CC(C)(C)C)CP(S)(=S)CC(C)CC(C)(C)C

InChI

1S/C16H35PS2/c1-13(9-15(3,4)5)11-17(18,19)12-14(2)10-16(6,7)8/h13-14H,9-12H2,1-8H3,(H,18,19)

InChI key

YOCZZJWFWDUAAR-UHFFFAOYSA-N

General description

Diisooctyldithiophosphinic acid has been reported as soft base. As per Pearson′s Hard and Soft Acids and Bases principle since soft base has an affinity for soft acid, it exhibits high affinity for soft cations.

Application

Diisooctyldithiophosphinic acid (bis(2,4,4-trimethyl pentyl)dithiophosphinic acid, cyanex 301) may be used in the following studies:
  • As mobile carrier in the preparation of new supported liquid membrane (SLM) system, useful for the selective transport of bismuth ions.
  • As an efficient carrier for the preparation of bulk liquid membrane (BLM) system, utilized for the transport of methylene blue.
  • As carrier in the preparation of a novel bulk liquid membrane (BLM) system, used to evaluate mercury transport and recovery of the ions from acidic nitrate solutions.
Complexing agent for the extraction of transition metals


signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

75.2 °F - closed cup

flash_point_c

24 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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Highly efficient and selective transport of methylene blue through a bulk liquid membrane containing Cyanex 301 as carrier.
Madaeni SS, et al.
Separation and Purification Technology, 81(2), 116-123 (2011)
Effects of membrane characteristics on selective transport of bismuth ion through supported liquid membrane
Madaeni SS and Karami Zand HR.
9th Iranian Chemical Engineering Congress (IChEC9), Iran University of Science and Technology (IUST, 23, 25-25 (2004)
Selective transport of bismuth ions through supported liquid membrane.
Madaeni SS and Karami Zand HR.
Chemical Engineering & Technology, 28(8), 892-892 (2005)



全球贸易项目编号

货号GTIN
381802-5G04061831810745