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Merck
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About This Item

线性分子式:
HC≡CCH2Cl
CAS Number:
分子量:
74.51
Beilstein:
506005
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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表单

liquid

浓度

70 wt. % in toluene

折射率

n20/D 1.456

密度

0.963 g/mL at 25 °C

官能团

alkyl halide
chloro

储存温度

2-8°C

SMILES字符串

ClCC#C

InChI

1S/C3H3Cl/c1-2-3-4/h1H,3H2

InChI key

LJZPPWWHKPGCHS-UHFFFAOYSA-N

一般描述

Product is the 70wt.% solution of propargyl chloride in toluene. Propargyl chloride is a propargyl halide. Its trimethylsilylation reaction has been reported. Liquid-phase Raman spectra, and vapor-phase and solution-phase infrared spectra of propargyl chloride has been studied at 100-3400cm-1 and 300-3800cm-1, respectively. It participates in the addition reaction with acyclic 1,3-dienes (at -78°C) in the presence of zinc chloride.

应用

Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8. It may be used for the in situ preparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols.
Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

66.2 °F

闪点(°C)

19 °C


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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