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经验公式(希尔记法):
C10H10F6FeP
化学文摘社编号:
分子量:
331.00
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
六氟磷酸盐二茂铁, 97%
SMILES string
[Fe+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F
InChI
1S/2C5H5.F6P.Fe/c2*1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-5H;;/q;;-1;+1
InChI key
JTRCXNUQIANBAN-UHFFFAOYSA-N
assay
97%
form
powder
reaction suitability
core: iron, reagent type: catalyst
Quality Level
Application
二茂铁正离子已被用于制备以下反应的催化剂:烯烃的不对称环氧化、硝基芳香化合物的羰基化和应力二烯的异构化。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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A series of mixed-valent (MV) complexes [(FeCp)2(mu-C10H6(BPh)2)]+X ([1+]X; X=I 5, PF6, SbF6, B(C6F5)4) were prepared by oxidation of diboradiferrocene [(FeCp)2(mu-C10H6(BPh)2)] (1) with I 2, AgPF6, and AgSbF6, respectively, and through anion exchange of the I 5(-) salt with [Li(Et2O)x][B(C6F5)4] in
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