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Merck
CN

388297

六氟磷酸盐二茂铁

97%, powder

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关于此项目

经验公式(希尔记法):
C10H10F6FeP
化学文摘社编号:
分子量:
331.00
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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产品名称

六氟磷酸盐二茂铁, 97%

SMILES string

[Fe+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F

InChI

1S/2C5H5.F6P.Fe/c2*1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-5H;;/q;;-1;+1

InChI key

JTRCXNUQIANBAN-UHFFFAOYSA-N

assay

97%

form

powder

reaction suitability

core: iron, reagent type: catalyst

Quality Level

Application

二茂铁正离子已被用于制备以下反应的催化剂:烯烃的不对称环氧化、硝基芳香化合物的羰基化和应力二烯的异构化。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Johanna Karppi et al.
Frontiers in chemistry, 8, 11-11 (2020-02-13)
Pyranose dehydrogenases (PDHs; EC 1.1.99.29; AA3_2) demonstrate ability to oxidize diverse carbohydrates. Previous studies of these enzymes have also uncovered substrate-dependent regioselectivity, along with potential to introduce more than one carbonyl into carbohydrate substrates. Enzymatic oxidation of carbohydrates facilitates their
Giorgia Zampardi et al.
Physical chemistry chemical physics : PCCP, 19(41), 28381-28387 (2017-10-17)
High voltage operating active materials are among the most promising components for positive electrodes of future high energy lithium-ion batteries. However, the operating potential range of such materials often exceeds anodically the thermodynamic stability window of the electrolyte. A surface
Go Tajima et al.
Molecular genetics and metabolism, 119(4), 322-328 (2016-11-20)
Medium-chain acyl-CoA dehydrogenase (MCAD) deficiency is a representative disorder of fatty acid oxidation and is one of the most prevalent inborn errors of metabolism among Caucasian populations. In Japan, however, it was as late as 2000 when the first patient
Inorganic Chemistry, 30, 3626-3626 (1991)
Krishnan Venkatasubbaiah et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(2), 444-458 (2007-12-12)
A series of mixed-valent (MV) complexes [(FeCp)2(mu-C10H6(BPh)2)]+X ([1+]X; X=I 5, PF6, SbF6, B(C6F5)4) were prepared by oxidation of diboradiferrocene [(FeCp)2(mu-C10H6(BPh)2)] (1) with I 2, AgPF6, and AgSbF6, respectively, and through anion exchange of the I 5(-) salt with [Li(Et2O)x][B(C6F5)4] in

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