388432
2-氨基甲基-18-冠-6
95%
别名:
1,4,7,10,13,16-Hexaoxacyclooctadecane-2-methanamine
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关于此项目
经验公式（希尔记法）:
C13H27NO6
化学文摘社编号:
分子量:
293.36
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4184588
Assay:
95%
Form:
liquid
InChI
1S/C13H27NO6/c14-11-13-12-19-8-7-17-4-3-15-1-2-16-5-6-18-9-10-20-13/h13H,1-12,14H2
SMILES string
NCC1COCCOCCOCCOCCOCCO1
InChI key
BJUGHLWDFGGTGJ-UHFFFAOYSA-N
assay
95%
form
liquid
refractive index
n20/D 1.479 (lit.)
bp
135 °C/0.08 mmHg (lit.)
density
1.126 g/mL at 25 °C (lit.)
Application
2-Aminomethyl-18-crown-6 (AM-18-C-6) can be used to prepare:
- AM-18-C-6 bonded Merrifield peptide resin, which is used to study the absorption and the isotopic effect of magnesium.
- Schiff base of gossypol with aminomethyl crown ether for complexation of monovalent cations.
- Crown tagged triarylphosphine by reacting with triphenylphosphine carboxylic acid. These tagged triarylphosphine reagents are used in Mitsunobu and Heck reactions for the removal of phosphine derived by-products.
- 1,16-hexadecanoyl-bis-(2-aminomethyl)-18-crown-6 (bola A-16), which is utilized as a vesicular carrier in a drug delivery system.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Adsorption and isotope effects by ion exchange with aqueous-2-aminomethyl-18-crown-6 bonded Merrifield resin
Kim DW, et al.
Journal of Colloid and Interface Science, 254(1), 190-194 (2002)
A new crown ether as vesicular carrier for 5-fluoruracil: synthesis, characterization and drug delivery evaluation
Muzzalupo R, et al.
Colloids and Surfaces. B, Biointerfaces, 58(2), 197-202 (2007)
Synthesis and application of crown ether tagged triarylphosphines
Jackson, Toby and Routledge, Anne
Tetrahedron Letters, 44(6), 1305-1307 (2003)
The Schiff base of gossypol with 2-(aminomethyl)-18-crown-6 complexes and H+, Li+, Na+, K+, Rb+, Cs+ cations studied by ESI MS, 1H NMR, FT-IR and PM5 semiempirical methods
Przybylski P, et al.
Journal of Molecular Structure, 699(1-3), 65-77 (2004)
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