390992
2,4,6-三叔丁基-N-甲苯胺
95%
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关于此项目
线性分子式:
[(CH3)3C]3C6H2NHCH3
化学文摘社编号:
分子量:
275.47
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
powder
InChI
1S/C19H33N/c1-17(2,3)13-11-14(18(4,5)6)16(20-10)15(12-13)19(7,8)9/h11-12,20H,1-10H3
SMILES string
CNc1c(cc(cc1C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI key
GFTNLYGZUUPSSM-UHFFFAOYSA-N
assay
95%
form
powder
mp
109-111 °C (lit.)
functional group
amine
General description
2,4,6-Tri-tert-butyl-N-methylaniline, a sterically hinderd amine, is an aniline derivative. The steric effect on charge-transfer (CT) band in its electronic spectra has been reported. The reactivity of 2,4,6-tri-tert-butyl-N-methylaniline with alkyl iodides under high pressure has been reported.
Application
2,4,6-Tri-tert-butyl-N-methylaniline may be used in the synthesis of 2,5-di-tert-butyl-N,N-dimethylanilinium iodide and 2,5-di-tert-butyl-N-ethyl-N-ethylanilinium iodide.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Steric hindrance under high pressure. Reactions of 2, 4, 6-tri-tert-butyl-N-methylaniline with alkyl iodides.
Okamoto Y and Shimizu H.
Journal of the American Chemical Society, 90(22), 6145-6148 (1968)
Suzuki H
Electronic absorption spectra and geometry of organic molecules: An application of molecular orbital theory (Elsevier), 485-485 (2012)
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