392413
2,3-二苄基-1,3-丁二烯
99%
方案
99%
mp
86-88 °C (dec.) (lit.)
储存温度
2-8°C
SMILES字符串
C=C(Cc1ccccc1)C(=C)Cc2ccccc2
InChI
1S/C18H18/c1-15(13-17-9-5-3-6-10-17)16(2)14-18-11-7-4-8-12-18/h3-12H,1-2,13-14H2
InChI key
FNCJMHZWHWRYEO-UHFFFAOYSA-N
一般描述
2,3-Dibenzyl-1,3-butadiene is a disubstituted-1,3-butadiene. It participates in the synthesis of 2,3-dibenzyl-1,3-butadiene. It participates in the synthesis of η3:η1-allylalkoxynickel complex.
应用
2,3-Dibenzyl-1,3-butadiene may be used in the cycloaddition reaction with donor-stabilized silylene and 1,2-diketones to form the corresponding cycloaddition products. It may be used to form cyclopentenones by dienyl-Pauson-Khand reaction with suitable alkynes.
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Bis [N, N'-diisopropylbenzamidinato (-)] silicon (II): Cycloaddition Reactions with Organic 1, 3-Dienes and 1, 2-Diketones.
Laskowski N, et al.
Organometallics, 33(21), 6141-6148 (2014)
The Diene Effect: The Design, Development, and Mechanistic Investigation of Metal-Catalyzed Diene-yne, Diene-ene, and Diene-allene [2+ 2+ 1] Cycloaddition Reactions.
Croatt MP and Wender PA.
European Journal of Organic Chemistry, 2010(1), 19-32 (2010)
Sensuke Ogoshi et al.
Journal of the American Chemical Society, 128(21), 7077-7086 (2006-05-25)
The reversible oxidative cyclization of dienes and aldehydes with nickel(0) proceeded to give eta(3):eta(1)-allylalkoxynickel complexes. The treatment of these complexes with carbon monoxide led to the formation of the corresponding lactone and/or the regeneration of a butadiene and an aldehyde
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