394424
(烯丙氧基羰甲基)三苯基碘化膦
97%
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关于此项目
线性分子式:
(C6H5)3P(CH2CO2CH2CH=CH2)I
化学文摘社编号:
分子量:
488.30
UNSPSC Code:
12352108
PubChem Substance ID:
MDL number:
Assay:
97%
InChI
1S/C23H22O2P.HI/c1-2-18-25-23(24)19-26(20-12-6-3-7-13-20,21-14-8-4-9-15-21)22-16-10-5-11-17-22;/h2-17H,1,18-19H2;1H/q+1;/p-1
SMILES string
[I-].C=CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI key
PJGRTFGJXKYEIH-UHFFFAOYSA-M
assay
97%
reaction suitability
reaction type: C-C Bond Formation
mp
138 °C (dec.) (lit.)
Application
用于由醛和酮制备 α,β-不饱和酯。烯丙基可被标准铑或钯催化化学反应轻易移除。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
H Vyplel et al.
Journal of medicinal chemistry, 34(9), 2759-2767 (1991-09-01)
The synthesis of a series of novel analogues of lipid A, the lipophilic terminal of lipopolysaccharides (LPS), and lipid X, the reducing monosaccharide unit in lipid A, is reported. In these compounds, the native 1-O-phosphate group has been replaced by
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