394483
环丁基甲基酮
98%
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
C4H7COCH3
化学文摘社编号:
分子量:
98.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
221-163-6
MDL number:
Assay:
98%
Form:
liquid
form
liquid
InChI key
JPJOOTWNILDNAW-UHFFFAOYSA-N
InChI
1S/C6H10O/c1-5(7)6-3-2-4-6/h6H,2-4H2,1H3
SMILES string
CC(=O)C1CCC1
assay
98%
refractive index
n20/D 1.432 (lit.)
bp
137-139 °C/754 mmHg (lit.)
density
0.902 g/mL at 25 °C (lit.)
Quality Level
General description
Cyclobutyl methyl ketone (CMK, methyl cyclobutyl ketone) is an alicyclic ketone. It has been synthesized by reacting cyclobutanecarbonyl chloride with magnesium salt of malonic ester. The mechanism of the photochemical reaction of gaseous mixtures of cyclobutyl methyl ketone diluted in argon has been studied by steady-state and pulsed (laser) photolysis. It′s infrared (3500 to 30cm-1) and Raman (3200 to 30cm-1) spectra in gaseous and solid state has been recorded. The UV spectra have been measured in alcohol and isooctane solution. Study on the vapour phase thermal and photodecomposition of methyl cyclobutyl ketone shows that the mode of decomposition is free radical in nature.
Application
Cyclobutyl methyl ketone may be used as a model compound to study the oxidation mechanism of pinonic acid by hydroxyl radicals.
Cyclobutyl methyl ketone as a model compound for pinonic acid to elucidate oxidation mechanisms.
Praplan AP, et al
Atmospheric Chemistry and Physics, 12(22), 10749-10758 (2012)
Structure and Reactivity in the Vapor Phase Photolysis of Ketones. III. Methyl Cyclobutyl Ketone1,2.
Norman I and Pitts Jr. JN
Journal of the American Chemical Society, 77(23), 6104-6107 (1955)
Spectra and structure of small ring molecules: Part XLIV. Vibrational spectra and conformational stability of cyclobutylmethyl ketone.
Durig JR, et al
Journal of Molecular Structure, 125(3-4), 211-227 (1984)
Azo-bis Nitriles. 1 Decomposition of Azo Compounds. A Special Case of Carbon-Carbon Hyperconjugation in a Free Radical Reaction.
Overberger CG and Lebovits A
Journal of the American Chemical Society, 76(10), 2722-2725 (1954)
Ultraviolet Absorption Spectra of Alicyclic Compounds. II. Methyl Cycloalkyl Ketones1.
Mariella RP and Raube RR
Journal of the American Chemical Society, 74(2), 518-521 (1952)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持