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396222

1-氯-4-碘丁烷

Name: 1-氯-4-碘丁烷
Brand: ALDRICH

98%

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关于此项目

线性分子式:

I(CH₂)₄Cl

化学文摘社编号:

10297-05-9

分子量:

218.46

NACRES:

NA.22

PubChem Substance ID:

24864660

UNSPSC Code:

12352100

EC Number:

233-669-4

MDL number:

MFCD00039415

Assay:

98%

Form:

liquid

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属性

Quality Level

100

assay

98%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.54 (lit.)

bp

88-89 °C/19 mmHg (lit.)

density

1.785 g/mL at 25 °C (lit.)

functional group

chloro, iodo

SMILES string

ClCCCCI

InChI

1S/C4H8ClI/c5-3-1-2-4-6/h1-4H2

InChI key

JXOSPTBRSOYXGC-UHFFFAOYSA-N

说明

General description

1-Chloro-4-iodobutane is a halogenated hydrocarbon. It is an α,ω-dihaloalkane and undergoes electrogenerated Nickel(I) salen (N,N′-bis(salicylidene)ethylenediamine) catalyzed reduction to afford 1,8-dichlorooctane. Electrochemical reduction of 1-chloro-4-iodobutane at glassy carbon cathode has been investigated by cyclic voltammetry and controlled-potential electrolysis.

Application

1-Chloro-4-iodobutane may be used in the following studies:

Preparation of 6-hendecenoic acid.
Catalytic asymmetric synthesis of levobupivacaine.
Synthesis of alkaloids such as deoxyvasicinone, mackinazolinone.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

199.4 °F - closed cup

flash_point_c

93 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Studies directed towards asymmetric synthesis of levobupivacaine.

Kumar S and Ramachandran U.

Tetrahedron Letters, 46(1), 19-21 (2005)

The synthesis of unsaturated fatty acids.

K AHMAD et al.

Journal of the American Chemical Society, 70(5), 1699-1699 (1948-05-01)

Radical reactions with 3H-quinazolin-4-ones: synthesis of deoxyvasicinone, mackinazolinone, luotonin A, rutaecarpine and tryptanthrin.

W Russell Bowman et al.

Organic & biomolecular chemistry, 5(1), 103-113 (2006-12-14)

Alkyl, aryl, heteroaryl and acyl radicals have been cyclised onto the 2-position of 3H-quinazolin-4-one. The side chains containing the radical precursors were attached to the nitrogen atom in the 3-position. The cyclisations take place by aromatic homolytic substitution hence retain

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全球贸易项目编号

货号	GTIN
396222-25ML	04061837073397
396222-5ML	04061837073403