396478
2-吡啶基三氟甲磺酸酯
98%
别名:
2-吡啶基三氟甲基磺酸酯
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关于此项目
经验公式（希尔记法）:
C6H4F3NO3S
化学文摘社编号:
分子量:
227.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
Form:
liquid
InChI
1S/C6H4F3NO3S/c7-6(8,9)14(11,12)13-5-3-1-2-4-10-5/h1-4H
SMILES string
FC(F)(F)S(=O)(=O)Oc1ccccn1
InChI key
COLRMVLTWJTLFJ-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.435 (lit.)
bp
108 °C/25 mmHg (lit.)
density
1.477 g/mL at 25 °C (lit.)
functional group
fluoro, triflate
Quality Level
General description
2-Pyridyl trifluoromethanesulfonate is a heterocyclic building block.
Application
2-Pyridyl trifluoromethanesulfonate (2-Pyridyl triflate) may be used in the preparation of pyridinium salts [R-iso-BIPY-H]+[OTF]- salts (R-iso-BIPY = N-(2-pyridyl)-R-pyridine-2-ylidene [R = 4-H, 4-tert-butyl, 4-dimethylamino, 5-dimethylamino]; OTf- = trifluoromethanesulfonate).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
80.6 °F - closed cup
flash_point_c
27 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Jonathan S Owen et al.
Journal of the American Chemical Society, 126(26), 8247-8255 (2004-07-01)
A series of [(R-iso-BIPY)Pt(CH(3))L ](+)X(-) complexes [R-iso-BIPY = N-(2-pyridyl)-R-pyridine-2-ylidene; (R = 4-H, 1; 4-tert-butyl, 2; 4-dimethylamino, 3; 5-dimethylamino, 4); L = SMe(2), b; dimethyl sulfoxide (DMSO), c; carbon monoxide (CO), d; X = OTf(-) = trifluoromethanesulfonate and/or [BPh(4)](-)] were synthesized
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