400386
丙烷 N,N-二甲基乙胺络合物 溶液
0.5 M in toluene
别名:
(乙二甲胺)三氢铝, N,N-二甲基乙胺醛烷络合物
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关于此项目
线性分子式:
C2H5N(CH3)2 · AlH3
化学文摘社编号:
分子量:
103.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Form:
liquid
form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
0.5 M in toluene
density
0.837 g/mL at 25 °C
functional group
amine
SMILES string
[AlH3].CCN(C)C
InChI
1S/C4H11N.Al.3H/c1-4-5(2)3;;;;/h4H2,1-3H3;;;;
InChI key
CXNFERZVFRNSPE-UHFFFAOYSA-N
Application
丙烷 N,N-二甲基乙胺络合物溶液可作为选择性还原剂，用于还原溴代 γ-内酰胺类合成二氢氟胺 C 和氟胺 E 生物碱。
作为以下反应的反应物：
- 铝纳米颗粒的制备
- 氟化反应
- 用于铝膜的生长的铝金属有机化学气相沉积反应
- 配体交换反应
- 腈和异腈的水铝化反应
signalword
Danger
target_organs
Central nervous system
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-4.0 °F
flash_point_c
-20 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3 - Water-react. 2
法规信息
危险化学品
易制毒化学品（3类）
此项目有
First total syntheses of dihydroflustramine C and flustramine E, alkaloids from the marine bryozoan Flustra foliacea.
Morales-Rios MS, et al.
Tetrahedron, 58(8), 1479-1484 (2002)
Hossein Robatjazi et al.
Science advances, 5(2), eaav5340-eaav5340 (2019-02-21)
Metal-organic frameworks (MOFs) and metal nanoparticles are two classes of materials that have received considerable recent attention, each for controlling chemical reactivities, albeit in very different ways. Here, we report the growth of MOF shell layers surrounding aluminum nanocrystals (Al
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 400386-50ML | 04061831984927 |
| 400386-100ML | 04061838127136 |