401358
(S)-(-)-N,α-二甲基苯甲基胺
98%
别名:
(S)-(-)-N-甲基-1-苯乙胺
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关于此项目
线性分子式:
C6H5CH(CH3)NHCH3
化学文摘社编号:
分子量:
135.21
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1446867
Assay:
98%
Form:
liquid
InChI
1S/C9H13N/c1-8(10-2)9-6-4-3-5-7-9/h3-8,10H,1-2H3/t8-/m0/s1
SMILES string
CN[C@@H](C)c1ccccc1
InChI key
RCSSHZGQHHEHPZ-QMMMGPOBSA-N
assay
98%
form
liquid
optical activity
[α]20/D −73±5°, c = 2 in chloroform
refractive index
n20/D 1.512 (lit.)
bp
74-76 °C/11 mmHg (lit.)
density
0.928 g/mL at 20 °C (lit.)
functional group
amine, phenyl
General description
(S)-(-)-N,a-Dimethylbenzylamine may be used along with benzaldehyde in the Mannich-type aminoalkylation of 2-naphthol to form 1-((S)-phenyl(((1′S)-1′-phenylethyl)methylamino)methyl)-2-naphthol. This optically active tertiary aminonaphthol can catalyze the enantioselective alkenylation of various aldehyde to generate chiral (E)- allyl alcohols.
Application
用于制备不对称有机金属催化剂（如，用于共轭加成反应生成烯酮）。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
141.8 °F - closed cup
flash_point_c
61 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
A convenient, one-step synthesis of optically active tertiary aminonaphthol and its applications in the highly enantioselective alkenylations of aldehydes
J JX, et al.
The Journal of Organic Chemistry, 68(4), 1589-1590 (2003)
Tetrahedron Letters, 31, 965-965 (1990)
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