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Merck
CN

40577

Sigma-Aldrich

(S)-1-辛烯-3-醇

≥95% (sum of enantiomers, GC)

别名:

(S)-松茸醇

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关于此项目

经验公式(希尔记法):
C8H16O
化学文摘社编号:
分子量:
128.21
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
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方案

≥95% (sum of enantiomers, GC)

表单

liquid

光学纯度

enantiomeric ratio: ≥99:1 (GC)

官能团

hydroxyl

SMILES字符串

CCCCC[C@H](O)C=C

InChI

1S/C8H16O/c1-3-5-6-7-8(9)4-2/h4,8-9H,2-3,5-7H2,1H3/t8-/m1/s1

InChI key

VSMOENVRRABVKN-MRVPVSSYSA-N

应用

(S)-1-Octen-3-ol can be used:
  • As an odorant in the study of an olfactory sensory map of the Anopheles gambiae maxillary palp.
  • As an intermediate in the synthesis of natural product polyporolide and a prostaglandin named 8-aza-prostaglandin E1.
  • As a substrate in the preparation of trienols by reacting with 1-iodo-1,3-dienes using Pd(OAc)2/AgOAc.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

154.4 °F - closed cup

闪点(°C)

68 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

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A stereoselective synthesis of the reported structure of polyporolide
Patil PH and Fernandes RA
Royal Society of Chemistry Advances, 5(61), 49189-49194 (2015)
Jonathan D Bohbot et al.
PloS one, 4(9), e7032-e7032 (2009-09-16)
Enantiomers differ only in the left or right handedness (chirality) of their orientations and exhibit identical chemical and physical properties. In chemical communication systems, enantiomers can be differentially active at the physiological and behavioral levels. Only recently were enantioselective odorant
Odor coding in the maxillary palp of the malaria vector mosquito Anopheles gambiae
Lu T, et al.
Current Biology, 17(18), 1533-1544 (2007)
Alan J Grant et al.
PloS one, 6(6), e21785-e21785 (2011-07-09)
1-Octen-3-ol (octenol) is a common attractant released by vertebrates which in combination with carbon dioxide (CO(2)) attracts hematophagous arthropods including mosquitoes. A receptor neuron contained within basiconic sensilla on the maxillary palps of adult mosquitoes responds selectively to 1-octen-3-ol. Recently
Xiao-Gang Wang et al.
The Journal of organic chemistry, 78(18), 9488-9493 (2013-08-21)
We report herein for the first time the enantioselective synthesis of 8-aza-PGE1. The synthesis used the cross olefin metathesis reaction to connect the 5-vinyl-γ-lactam subunit, prepared from (R)-malic acid via the Ley's sulfone-based α-amidalkylation protocol (dr = 6.8:1), with the

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