414670
1-碘-2-三甲基硅基乙炔
97%
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关于此项目
线性分子式:
(CH3)3SiC≡CI
化学文摘社编号:
分子量:
224.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
liquid
产品名称
1-碘-2-三甲基硅基乙炔, 97%
InChI
1S/C5H9ISi/c1-7(2,3)5-4-6/h1-3H3
SMILES string
C[Si](C)(C)C#CI
InChI key
HNIRHTRSZDSMOF-UHFFFAOYSA-N
assay
97%
form
liquid
refractive index
n20/D 1.511 (lit.)
bp
130 °C (lit.)
density
1.46 g/mL at 25 °C (lit.)
functional group
iodo
storage temp.
2-8°C
Quality Level
Application
1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
118.4 °F - closed cup
flash_point_c
48 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Elodie E Marlier et al.
Inorganic chemistry, 51(4), 2079-2085 (2012-02-11)
A model for cobalamin was synthesized using a new monoanionic tetradentate nitrogen donor ligand; 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine (Tol-BDI((2-pp)2)H) (1), which utilizes isopropylpyridines as pendant arms on a β-diketiminate (BDI) backbone. During the synthesis of 1, the rearrangement product, Tol-BDI((2-pp)(4-pp))H (2) was observed.
Novel polyacetylenes containing pendant 1-pyrenyl groups: synthesis, characterization, and thermal and optical properties.
Rivera E, et al.
Polymer, 43(19), 5059-5068 (2009)
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