InChI
1S/2ClH.Mn/h2*1H;/q;;+2/p-2
SMILES string
Cl[Mn]Cl
InChI key
GLFNIEUTAYBVOC-UHFFFAOYSA-L
assay
97%
form
flakes
reaction suitability
core: manganese, reagent type: catalyst
mp
652 °C (lit.)
density
2.98 g/mL at 25 °C (lit.)
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Application
制备有机锰氯化物试剂的起始物料;还原共催化剂乙烯基和芳基卤化物的立体选择性偶联、乙烯基碘化物的立体选择性偶联以及烯醇三氟酸盐的烷基化。
通过 MnCl 2 氧化,合成了一种具有同时促进聚合的高自旋六核 Mn (Ⅲ) 团簇 [NaMn 6 (OMe) 12 (dbm) 6 ] + 。该团簇具有前所未有的环状结构和 24 个处于基态的未配对电子。也用于形成对自由基环化反应有用的活性 Mn (0) 物种。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2
target_organs
Brain
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Abbati, G.L. et al.
Inorganic Chemistry, 37, 1430-1430 (1998)
Tang, J. et al.
Tetrahedron, 55, 1893-1893 (1999)
Asad A Aboud et al.
Neurotoxicology, 33(6), 1443-1449 (2012-10-27)
Manganese (Mn) is an environmental risk factor for Parkinson's disease (PD). Recessive inheritance of PARK2 mutations is strongly associated with early onset PD (EOPD). It is widely assumed that the influence of PD environmental risk factors may be enhanced by
Tora Sund Morken et al.
Pediatric research, 73(2), 171-179 (2012-11-24)
Hypoxia-ischemia (HI) induces delayed inflammation and long-term gray and white matter brain injury that may be altered by hyperoxia. HI and 2 h of hyperoxia (100% O2) or room air (21% O2) in 7-d-old (P7) rats were studied by magnetic resonance
M R Sepúlveda et al.
Contrast media & molecular imaging, 7(4), 426-434 (2012-06-01)
Manganese is a vital element and cofactor of many key enzymes, but it is toxic at high levels, causing pronounced disturbances in the mammalian brain. Magnetic resonance imaging (MRI) studies using manganese ions as a paramagnetic contrast agent are often
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