Quality Level
assay
≥95%
form
powder
mp
262-265 °C (lit.)
functional group
fluoro
SMILES string
OB(O)c1ccc(F)cc1
InChI
1S/C6H6BFO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChI key
LBUNNMJLXWQQBY-UHFFFAOYSA-N
Application
4-氟基苯硼酸可用作反应物，参与四氟硼酸芳香重氮盐、 碘鎓盐和碘烷的偶联反应。它还被用于生产具有生物活性的新型三联苯。
它也可作为反应物参与：
它也可作为反应物参与：
- 使用微波和triton B催化剂的Suzuki偶联。
- Pd催化的吡唑与苯硼酸的直接芳基化反应。
- 钯纳米粒子催化的 Mizoroki-Heck 和 Suzuki-Miyaura 偶联反应。
- Cu催化的Petasis反应。
- 串联型Pd(II)催化的氧化Heck反应和分子内C-H酰胺化序列。
- 钌催化的直接芳基化。
- Rh催化的不对称耦合物加合。
- 无配体铜催化的硝基芳烃与芳基硼酸的偶联。
- 通过Suzuki-Miyaura和Sonogashira交叉偶联反应进行区域选择性芳基化和炔基化。
- 四溴噻吩的Suzuki交叉偶联。
- 腈的钯催化加成。
Other Notes
含不定量的酸酐
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
相关内容
Robin Frauenlob et al.
The Journal of organic chemistry, 77(9), 4445-4449 (2012-04-13)
We have developed a copper-catalyzed process for the coupling of aldehydes, amines, and boronic acids. This allows greater reactivity with simple aryl boronic acids and allows coupling reactions to proceed that previously failed. Initial mechanistic studies support a process involving
Suk-Ku Kang et al.
The Journal of organic chemistry, 61(14), 4720-4724 (1996-07-12)
The palladium-catalyzed cross-coupling reaction of iodinanes (iodonium salts and iodanes) with organoboron compounds to form carbon-carbon bonds was achieved at ambient temperature under aqueous conditions in the absence of base. Coupling of phenylboronic acid with diphenyliodonium tetrafluoroborate in the presence
Microwave-enhanced triton B catalyzed Suzuki coupling reaction
Meshram, H. M.; et al.
Indian J. Chem. B, 51, 362-365 (2012)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 417556-25G | 04061832090290 |
| 417556-5G | 04061832090337 |
| 417556-1G | 04061832090269 |