Merck
CN

418064

Sigma-Aldrich

叔丁基过氧化氢 溶液

5.0-6.0 M in nonane

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别名:
1,1-二甲基乙基-过氧化氢, 2-过氧化氢-2-甲基丙烷, TBHP
线性分子式:
(CH3)3COOH
CAS号:
分子量:
90.12
Beilstein:
1098280
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

形式

liquid

质量水平

reaction suitability

reagent type: oxidant

浓度

5.0-6.0 M in nonane

杂质

<4% water

折射率

n20/D 1.399

密度

0.817 g/mL at 25 °C

储存温度

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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此商品
458139416665328650
Potassium tert-butoxide solution 1.0&#160;M in THF

Sigma-Aldrich

328650

叔丁醇钾 溶液

concentration

5.0-6.0 M in nonane

concentration

12.25-14.20% (active oxygen), 69.0-80.0% (NH2OH, titration), 70 wt. % in H2O

concentration

5.0-6.0 M in decane, 55.4-65.1% (Thiosulphate, titration)

concentration

1.0 M in THF

refractive index

n20/D 1.399

refractive index

n20/D 1.386

refractive index

n20/D 1.402

refractive index

-

density

0.817 g/mL at 25 °C

density

0.93 g/mL at 25 °C

density

0.808 g/mL at 25 °C

density

0.902 g/mL at 25 °C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

reagent type: oxidant

reaction suitability

-

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1

储存分类代码

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

闪点(°F)

84.2 °F - closed cup

闪点(°C)

29 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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A new synthetic approach toward direct C-N bond formation through sp(3) C-H activation has been developed under metal-free conditions. Both primary and secondary benzylic C-H substrates could react smoothly with various amines to give only mono-amination products with good to
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Oligomeric and polymeric procyanidins have been reported to possess different antioxidant capacities. However, the intracellular antioxidant mechanisms of oligomeric and polymeric procyanidins are still poorly understood. In this study, we evaluated the cytoprotective effects of the oligomeric procyanidin fraction (OPF)
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This protocol describes a new approach for the preparation of stereodefined trisubstituted chiral enolate species, avoiding conventional asymmetric enolization of carbonyl compounds. This protocol was developed as a single-flask synthetic sequence and therefore does not require isolation or purification of
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This work investigated the ultrasonic assisted oxidative desulfurization of bunker-C oil with TBHP/MoO3 system. The operational parameters for the desulfurization procedure such as ultrasonic irradiation time, ultrasonic wave amplitude, catalyst initial concentration and oxidation agent initial concentration were studied. The

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