42140
2,7-二硝基甲酚
≥95.0% (HPLC)
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关于此项目
经验公式（希尔记法）:
C10H6N2O4
化学文摘社编号:
分子量:
218.17
Beilstein:
2214687
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
方案
≥95.0% (HPLC)
mp
229-233 °C
SMILES字符串
[O-][N+](=O)c1ccc2ccc(cc2c1)[N+]([O-])=O
InChI
1S/C10H6N2O4/c13-11(14)9-3-1-7-2-4-10(12(15)16)6-8(7)5-9/h1-6H
InChI key
AFDWAIQLYHEUIW-UHFFFAOYSA-N
一般描述
Kinetics and ESR studies of intramolecular electron-transfer reactions of the radical anion of 2,7-dinitronaphthalene in various polar aprotic solvents has been studied. 2,7-Dinitronaphthalene undergoes mononitration to afford 1:3:6:8-tetranitronapthalene.
应用
2,7-Dinitronaphthalene has been used for the cyclodextrin distribution capillary electrochromatographic separation of naphthalene compounds.
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
法规信息
新产品
此项目有
107. The further nitration of 1: 3-, 1: 6-, 2: 6-, and 2: 7-dinitronaphthalenes, and the preparation of 1: 3: 6-trinitronaphthalene.
Edward, R.
Journal of the Chemical Society, 533-534 (1946)
M Culha et al.
Analytical chemistry, 72(1), 88-95 (2000-02-03)
Separations of naphthalene compounds that differ in position of substitution and type of substituent were accomplished using cyclodextrin distribution capillary electrochromatography. Separation systems composed of running buffers containing mixtures of native neutral and single isomer anionic cyclodextrins (CDs) were employed
João P Telo et al.
The journal of physical chemistry. A, 113(27), 7730-7736 (2009-06-10)
Rate constants for the intramolecular electron-transfer reaction in the 2,7-dinitronaphthalene (2(-)), 4,4'-dinitrotolane (3(-)), and 2,2'-dimethyl-4,4'-dinitrobiphenyl (4(-)) radical anions in several polar aprotic solvents were estimated by simulating their ESR spectra at different temperatures. At 298 K, the rate constants are
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