42140
2,7-二硝基甲酚
≥95.0% (HPLC)
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关于此项目
经验公式（希尔记法）:
C10H6N2O4
化学文摘社编号:
分子量:
218.17
EC Number:
246-480-7
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
2214687
MDL number:
Assay:
≥95.0% (HPLC)
InChI key
AFDWAIQLYHEUIW-UHFFFAOYSA-N
InChI
1S/C10H6N2O4/c13-11(14)9-3-1-7-2-4-10(12(15)16)6-8(7)5-9/h1-6H
SMILES string
[O-][N+](=O)c1ccc2ccc(cc2c1)[N+]([O-])=O
assay
≥95.0% (HPLC)
mp
229-233 °C
General description
Kinetics and ESR studies of intramolecular electron-transfer reactions of the radical anion of 2,7-dinitronaphthalene in various polar aprotic solvents has been studied. 2,7-Dinitronaphthalene undergoes mononitration to afford 1:3:6:8-tetranitronapthalene.
Application
2,7-Dinitronaphthalene has been used for the cyclodextrin distribution capillary electrochromatographic separation of naphthalene compounds.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
法规信息
新产品
此项目有
107. The further nitration of 1: 3-, 1: 6-, 2: 6-, and 2: 7-dinitronaphthalenes, and the preparation of 1: 3: 6-trinitronaphthalene.
Edward, R.
Journal of the Chemical Society, 533-534 (1946)
João P Telo et al.
The journal of physical chemistry. A, 113(27), 7730-7736 (2009-06-10)
Rate constants for the intramolecular electron-transfer reaction in the 2,7-dinitronaphthalene (2(-)), 4,4'-dinitrotolane (3(-)), and 2,2'-dimethyl-4,4'-dinitrobiphenyl (4(-)) radical anions in several polar aprotic solvents were estimated by simulating their ESR spectra at different temperatures. At 298 K, the rate constants are
M Culha et al.
Analytical chemistry, 72(1), 88-95 (2000-02-03)
Separations of naphthalene compounds that differ in position of substitution and type of substituent were accomplished using cyclodextrin distribution capillary electrochromatography. Separation systems composed of running buffers containing mixtures of native neutral and single isomer anionic cyclodextrins (CDs) were employed
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