421820
(1S)-(-)-莰烷酰氯
≥98%, ChiraSelect™
别名:
(-)-莰烷酰氯, (1S)-3-氧代-4,7,7-三甲基-2-氧杂双环[2.2.1]庚烷-1-甲酰氯
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关于此项目
线性分子式:
C10H13O3Cl
化学文摘社编号:
分子量:
216.66
EC Number:
254-552-4
UNSPSC Code:
12352005
PubChem Substance ID:
Beilstein/REAXYS Number:
3590860
MDL number:
product line
ChiraSelect™
assay
≥98%
optical purity
ee: 99% (GLC)
mp
71-73 °C (lit.)
storage temp.
2-8°C
SMILES string
CC1(C)[C@@]2(C)CC[C@@]1(OC2=O)C(Cl)=O
InChI
1S/C10H13ClO3/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3/t9-,10+/m0/s1
InChI key
PAXWODJTHKJQDZ-VHSXEESVSA-N
Application
外消旋醇的拆分剂。
Legal Information
ChiraSelect is a trademark of Sigma-Aldrich Co. LLC
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Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Journal of the Chemical Society. Perkin Transactions 1, 2899-2899 (1992)
The determination of the absolute configurations of diastereomers of (S)-camphanoyl 3-hydroxy-5-oxohexanoic acid derivatives by X-ray crystallography.
Kwai-Ming Cheung et al.
Angewandte Chemie (International ed. in English), 41(7), 1198-1202 (2002-12-20)
M Ruud-Christensen et al.
Journal of chromatography, 491(2), 355-366 (1989-07-21)
A reversed-phase high-performance liquid chromatographic assay has been developed for determination of (R)-(--)-and (S)-(+)-proxyphylline in human plasma. The procedure is based on liquid-solid extraction of proxyphylline from plasma followed by derivatization of extracted proxyphylline with (--)-camphanoyl chloride. The ratio between