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422886

(S)-(+)-2-(氨甲基)吡咯烷

Name: (<I>S</I>)-(+)-2-(氨甲基)吡咯烷
Brand: ALDRICH

97%

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关于此项目

经验公式（希尔记法）:

C₅H₁₂N₂

化学文摘社编号:

69500-64-7

分子量:

100.16

NACRES:

NA.22

PubChem Substance ID:

24866461

UNSPSC Code:

12352005

MDL number:

MFCD00191745

Assay:

97%

Form:

liquid

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属性

Quality Level

100

assay

97%

form

liquid

optical activity

[α]20/D +20°, c = 1 in chloroform

refractive index

n20/D 1.482 (lit.)

bp

65 °C/11 mmHg (lit.)

density

0.933 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

NC[C@@H]1CCCN1

InChI

1S/C5H12N2/c6-4-5-2-1-3-7-5/h5,7H,1-4,6H2/t5-/m0/s1

InChI key

AUKXFNABVHIUAC-YFKPBYRVSA-N

说明

General description

(S)-(+)-2-(Aminomethyl)pyrrolidine is a chiral vicinal diamine.

Application

(S)-(+)-2-(Aminomethyl)pyrrolidine can be used as an organocatalyst:

For the asymmetric transformation of (S)-alanine.
In the asymmetric α-fluorination of linear and branched aldehydes using N-fluorobenzenesulfonamide as the fluorinating agent.

It can also be used as a reactant to prepare Schiff base metal complexes with pyrrolidine fragment as a ligand in asymmetric synthesis.

用于合成具有抗癌活性的化合物。

pictograms

GHS02,GHS07

signalword

Warning

hcodes

H226,H315,H319,H335

pcodes

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

116.6 °F - closed cup

flash_point_c

47 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

SHBJ1826

08126AG

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商品

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

Dioxovanadium (V) complexes of Schiff bases derived from S-(+)-2-(aminomethyl) pyrrolidine and aromatic o-hydroxycarbonyl compounds: Synthesis, characterization and structure

Kwiatkowski E, et al.

Polyhedron, 25(15), 2809-2814 (2006)

Synthesis, antitumor activity, and nephrotoxicity of the optical isomers of 2-aminomethylpyrrolidine(1,1-cyclobutane-dicarboxylato)platinum(II).

K Morikawa et al.

Journal of pharmaceutical sciences, 80(9), 837-842 (1991-09-01)

The optical isomers of 2-aminomethylpyrrolidine(1,1-cyclobutane- dicarboxylato)platinum(II) (DWA2114, 1), which has potent antitumor activity against various tumors, were synthesized. They were examined for antitumor activity against Colon 26 carcinoma in a sc-iv system, and changes in urinary protein and sugar levels

Asymmetric Transformation of Alanine via Optically Labile Imidazolines

Shibata S, et al.

Bulletin of the Chemical Society of Japan, 52(10), 2938-2941 (1979)

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货号	GTIN
422886-250MG	04061832985862
422886-100MG	04061835973644
422886-500MG	04061837893964