Merck
CN
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文件

427691

Sigma-Aldrich

3-碘溴苄

95%

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别名:
α-Bromo-m-iodotoluene, 1-(Bromomethyl)-3-iodobenzene, 3-(Bromomethyl)iodobenzene, m-Iodobenzylbromide
线性分子式:
IC6H4CH2Br
CAS号:
49617-83-6
分子量:
296.93
MDL编号:
MFCD00019016
PubChem化学物质编号:
24866775
NACRES:
NA.22

质量水平

100

检测方案

95%

mp

46-51 °C (lit.)

SMILES字符串

BrCc1cccc(I)c1

InChI

1S/C7H6BrI/c8-5-6-2-1-3-7(9)4-6/h1-4H,5H2

InChI key

BACZSVQZBSCWIG-UHFFFAOYSA-N

一般描述

3-Iodobenzyl bromide (3-IBBr, m-iodobenzyl bromide) is a meta-isomer of iodobenzyl bromide. It can be synthesized by the bromination of m-iodotoluene.

应用

3-Iodobenzyl bromide (3-IBBr, m-iodobenzyl bromide) was used as a derivatization reagent for the extraction and purification of thiouracil (TU).
It may be used in the synthesis of the following:
  • meta-substituted phenylalanine derivatives
  • N6-substituted aristeromycin derivative
  • (N)-methanocarba-N6-(3-iodobenzyl)adenosine

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Julie A L Kiebooms et al.
Applied and environmental microbiology, 80(23), 7433-7442 (2014-09-28)
In recent years, the frequent detection of the banned thyreostat thiouracil (TU) in livestock urine has been related to endogenous TU formation following digestion of glucosinolate-rich Brassicaceae crops. Recently, it was demonstrated that, upon in vitro digestion of Brassicaceae, fecal
Reaction of some sulfonyl halides with trypsin.
Kuranova IP and Konareva NV.
Bulletin of the Academy of Sciences of the USSR, Division of chemical science, 22(10), 2251-2254 (1973)
Phase Transfer Catalyst (PTC) Catalyzed Alkylations of Glycinamides for Asymmetric Syntheses of alpha-Amino Acid Derivatives.
Park YS, et al.
Bull. Korean Chem. Soc., 22(9), 958-962 (2001)
K A Jacobson et al.
Journal of medicinal chemistry, 43(11), 2196-2203 (2000-06-08)
Adenosine receptor agonists have cardioprotective, cerebroprotective, and antiinflammatory properties. We report that a carbocyclic modification of the ribose moiety incorporating ring constraints is a general approach for the design of A(1) and A(3) receptor agonists having favorable pharmacodynamic properties. While
Barbara Woźniak et al.
Journal of veterinary research, 62(4), 511-517 (2019-02-08)
In the European Union, the use of thyreostatic drugs for fattening slaughter animals has been banned since 1981 under Council Directive 81/602/EEC. For protection of consumer health against unwanted residues and in compliance with Directive 96/23, each EU country must

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