429066
(3-溴丙氧基)-叔丁基二甲基硅烷
97%
别名:
(3-Bromopropoxy)(1,1-dimethylethyl)dimethylsilane, 1-((tert-Butyldimethylsilyl)oxy)-3-bromopropane, 1-Bromo-3-(tert-butyldimethylsiloxy)propane, 1-Bromo-3-[(tert-butyldimethylsilanyl)oxy]propane, 1-Bromo-3-[(tert-butyldimethylsilyl)oxy]propane, 3-((tert-Butyldimethylsilyl)oxy)-1-bromopropane
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关于此项目
线性分子式:
Br(CH2)3OSi(CH3)2C(CH3)3
化学文摘社编号:
分子量:
253.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C9H21BrOSi/c1-9(2,3)12(4,5)11-8-6-7-10/h6-8H2,1-5H3
SMILES string
CC(C)(C)[Si](C)(C)OCCCBr
InChI key
QGMROEZDWJTIDW-UHFFFAOYSA-N
assay
97%
form
liquid
contains
sodium carbonate as stabilizer
refractive index
n20/D 1.451 (lit.)
bp
182 °C (lit.)
density
1.093 g/mL at 25 °C (lit.)
functional group
bromo
storage temp.
2-8°C
Quality Level
General description
(3-Bromopropoxy)-tert-butyldimethylsilane is a bromo silyl ether.
Application
(3-Bromopropoxy)-tert-butyldimethylsilane may be used to introduce propanol functionality to many pharmaceuticals.
It may be used as an alkylating agent in the synthesis of the following:
It may be used as an alkylating agent in the synthesis of the following:
- N-[2-[N-[3-(tert-butyldimethylsilyloxy)propyl]-N-ethylamino]ethyl]phthalimide
- O-(3-tert-butyldimethylsilyloxypropyl)-N-(tert-butoxycarbonyl)-L-tyrosine methyl ester
- tert-butyldimethyl-[3-(3-methyl-2-nitrophenoxy)propoxy]silane
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
185.0 °F - closed cup
flash_point_c
85 °C - closed cup
法规信息
新产品
此项目有
Ramani R Ranatunge et al.
Journal of medicinal chemistry, 47(9), 2180-2193 (2004-04-16)
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A concise total synthesis of (+/-)-vigulariol.
J Stephen Clark et al.
Angewandte Chemie (International ed. in English), 46(3), 437-440 (2006-12-06)
Synthesis of O-(3-[18F] Fluoropropyl)-L-tyrosine (L-[18F] FPT) and its biological evaluation in 9L tumor bearing rat.
Moon BS, et al.
Bull. Korean Chem. Soc., 26(1), 91-96 (2005)
Mechanisms of ZnII-activated magnetic resonance imaging agents.
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