434876
氯仿-d
99.8 atom % D, contains 0.1 % (v/v) TMS
别名:
氘代氯仿
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关于此项目
线性分子式:
CDCl3
化学文摘社编号:
分子量:
120.38
UNSPSC Code:
12142201
NACRES:
NA.21
PubChem Substance ID:
EC Number:
212-742-4
Beilstein/REAXYS Number:
1697633
MDL number:
产品名称
氯仿-d, 99.8 atom % D, contains 0.1 % (v/v) TMS
InChI key
HEDRZPFGACZZDS-MICDWDOJSA-N
InChI
1S/CHCl3/c2-1(3)4/h1H/i1D
SMILES string
[2H]C(Cl)(Cl)Cl
isotopic purity
99.8 atom % D
assay
≥99.00%
form
liquid
contains
0.1 % (v/v) TMS
technique(s)
NMR: suitable
impurities
≤0.0100% water
water
refractive index
n20/D 1.444 (lit.)
bp
60.9 °C (lit.)
mp
−64 °C (lit.)
density
1.500 g/mL at 25 °C (lit.)
mass shift
M+1
Quality Level
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Application
Chloroform-d may be used in the synthesis of dichlorofluoromethane-d.
General description
Chloroform-d (deuterochloroform, CDCl3) is a deuterated NMR solvent containing 0.1 % (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. It may be synthesized by reacting trichloroacetophenone and sodium deuteroxide. The influence of the number of pulses on its multiphoton decomposition (MPD) has been studied. Infrared spectral studies of C-D stretching and bending motions of CDCl3 in different solvents have been investigated. The effect of chloroform-d on the interaction of water with activated carbons has been analyzed. The dependence of molecular reorientation of deuterated chloroform on pressure and temperature has been studied by Raman spectroscopy.
Other Notes
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Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3
target_organs
Central nervous system, Liver,Kidney
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
美国出口管控产品
此项目有
The effect of collisions in the multiphoton decomposition of chloroform-d.
McRae GA, et al.
J. Chem. Phys. , 92(10), 5997-6003 (1990)
Isotope Effect on Dissociation Probabilities in the Mass Spectra of Chloroform and Chloroform-d.
Dibeler VH and Bernstein RB.
J. Chem. Phys. , 19(4), 404-406 (1951)
Influence of organics on the structure of water adsorbed on activated carbons.
Turov VV, et al.
Journal of Colloid and Interface Science, 253(1), 23-34 (2002)
Raman study of molecular reorientation in liquid chloroform and chloroform-d under high pressure.
Schroeder J, et al.
J. Chem. Phys. , 69(12), 5479-5488 (1978)
Dichlorofluoromethane-d: a versatile solvent for VT-NMR experiments.
Siegel JS and Anet FAL.
The Journal of Organic Chemistry, 53(11), 2629-2630 (1988)
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