436836
2-噻吩硼酸
≥95.0%
别名:
2-噻吩硼酸, 噻吩-2-硼酸
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关于此项目
经验公式（希尔记法）:
C4H5BO2S
化学文摘社编号:
分子量:
127.96
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
112375
产品名称
2-噻吩硼酸, ≥95.0%
InChI
1S/C4H5BO2S/c6-5(7)4-2-1-3-8-4/h1-3,6-7H
SMILES string
OB(O)c1cccs1
InChI key
ARYHTUPFQTUBBG-UHFFFAOYSA-N
assay
≥95.0%
form
solid
mp
138-140 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
用作以下反应的试剂
用作以下制备反应的试剂
- 钯催化的Suzuki-Miyaura交叉偶联
- 烷基化、硼酸化、偶联反应、Suzuki偶联和芴基溴化物的卤化
- 耦合交替共聚物的链增长催化剂转移缩聚反应
- 生成富勒烯基硼酸酯的高氯酸铁催化富勒烯反应
- 无配体的Suzuki、Sonogashira和Heck交叉偶联反应
- 铜催化的硝化反应
- 几何松弛引起的在红色发光硼二甲基甲烷（BODIPY）中的大斯托克位移及其在荧光硫醇探针中的应用
用作以下制备反应的试剂
- 含氧多环芳基三联苯的光物理属性
- 通过N-烷基化、Suzuki偶联和溴化的供体-受体型聚合物的供体单元
- 基于氨基吡啶的有丝分裂激酶Nek2抑制剂，在癌症肿瘤中具有潜在的抗增殖作用
Other Notes
含有不定量的酸酐
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Man-Wah Tsang et al.
Biotechnology journal, 11(2), 257-265 (2015-08-08)
Rapid emergence of class C β-lactamases has urged an immediate need for developing class C β-lactamase specific inhibitors for effective clinical treatment. To facilitate the development of effective class C β-lactamase inhibitors, we propose a new approach for a rapid
Paolo Innocenti et al.
Journal of medicinal chemistry, 55(7), 3228-3241 (2012-03-13)
We report herein a series of Nek2 inhibitors based on an aminopyridine scaffold. These compounds have been designed by combining key elements of two previously discovered chemical series. Structure based design led to aminopyridine (R)-21, a potent and selective inhibitor
Brett VanVeller et al.
Journal of the American Chemical Society, 134(17), 7282-7285 (2012-04-19)
The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold enforces proximity of the alcohol and arene reacting partners and confers significant rigidity to the resulting
Yinghui Chen et al.
The Journal of organic chemistry, 77(5), 2192-2206 (2012-02-10)
2-Thienyl and 2,6-bisthienyl BODIPY derivatives (BS-SS and BS-DS) were prepared that show intense absorption (ε = 65000 M(-1) cm(-1) at 507 nm) and a large Stokes shift (96 nm) vs the small Stokes shift of typical BODIPY (<15 nm). Control
Chain-growth catalyst transfer polycondensation of a conjugated alternating copolymer
Ono, R. J.; Bielawski, C. W.
Polymeric Materials: Science and Engineering Preprints (2012)
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